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Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

Fuel efficiency for tractor/trailer combinations continues to be a key area of focus for manufacturers and suppliers in the commercial vehicle industry. Improved fuel economy of vehicles in transit can be achieved through reductions in aerodynamic drag, tire rolling resistance, and driveline losses. Fuel economy can also be increased by improving the efficiency of the thermal to mechanical energy conversion of the engine. One specific approach to improving the thermal efficiency of the engine is to implement a waste heat recovery (WHR) system that captures engine exhaust heat and converts this heat into useful mechanical power through use of a power fluid turbine expander. Several heat exchangers are required for this Rankine-based WHR system to collect and reject the waste heat before and after the turbine expander. The WHR condenser, which is the heat rejection component of this system, can be an additional part of the front-end cooling module.

Experiments were conducted on a turbocharged three cylinder automotive common rail diesel engine with port injection of butanol. This dual fuel engine was run with neat butanol and blends of water and butanol (up to 20% water by mass). Experiments were performed at a constant speed of 1800 rpm and a brake mean effective pressure of 11.8 bar (full load) at varying butanol to diesel energy share values while diesel was either injected as a single pulse or as twin pulses (Main plus Post). Open engine controllers were used for varying the injection parameters of diesel and butanol. Water butanol blends improved the brake thermal efficiency by a small extent because of better combustion phasing as compared to butanol without water. When the butanol to diesel energy share was high, auto-ignition of butanol occurred before the injection of diesel. This lowered the ignition delay of diesel and hence elevated the smoke level.

Use of biodiesel from non-edible vegetable oil as an alternative fuel to mineral diesel is attractive economically and environmentally. Diesel engines emit several harmful gaseous emissions and some of them are regulated worldwide, while countless others are not regulated. These unregulated species are associated with severe health hazards. Karanja biodiesel is a popular alternate fuel in South Asia and various governments are considering its large-scale implementation. Therefore it is important to study the possible adverse impact of this new alternate fuel. In this study, unregulated and regulated emissions were measured at varying engine speeds (1500, 2500 and 3500 rpm) for various engine loads (0%, 20%, 40%, 60%, 80% and 100% rated load) using 20% Karanja biodiesel blend (KB20) and diesel in a 4-cylinder 2.2L common rail direct injection (CRDI) sports utility vehicle (SUV) engine.

Gasoline direct injection (GDI) technology is already in use in four wheeler applications owing to the additional benefits in terms of better combustion and fuel economy. The air-assisted in-cylinder injection is the emerging technology for gasoline engines which works with low pressure injection systems unlike gasoline direct injection (GDI) system. GDI systems use high pressure fuel injection, which provides better combustion and reduced fuel consumption. It envisages small droplet size and low penetration rate which will reduce wall wetting and hydrocarbon emissions. This study is concerned with a CFD analysis of an air-assisted injection system to evaluate mixture spray characteristics. For the analysis, the air injector fitted onto a constant volume chamber (CVC) maintained at uniform pressure is considered. The analysis is carried out for various CVC pressures, mixture injection durations and fuel quantities so as to understand the effect on mixture spray characteristics.

Better understanding of flow phenomena inside the combustion chamber of a diesel engine and accurate measurement of flow parameters is necessary for engine optimization i.e. enhancing power output, fuel economy improvement and emissions control. Airflow structures developed inside the engine combustion chamber significantly influence the air-fuel mixing. In this study, in-cylinder air flow characteristics of a motored, four-valve diesel engine were investigated using time-resolved high-speed Tomographic Particle Imaging Velocimetry (PIV). Single cylinder optical engine provides full optical access of combustion chamber through a transparent cylinder and flat transparent piston top. Experiments were performed in different vertical planes at different engine speeds during the intake and compression stroke under motoring condition. For visualization of air flow pattern, graphite particles were used for flow seeding.

In this study, 3D air-flow-field evolution in a single cylinder optical research engine was determined using tomographic particle imaging velocimetry (TPIV) at different engine speeds. Two directional projections of captured flow-field were pre-processed to reconstruct the 3D flow-field by using the MART (multiplicative algebraic reconstruction technique) algorithm. Ensemble average flow pattern was used to investigate the air-flow behavior inside the combustion chamber during the intake and compression strokes of an engine cycle. In-cylinder air-flow characteristics were significantly affected by the engine speed. Experimental results showed that high velocities generated during the first half of the intake stroke dissipated in later stages of the intake stroke. In-cylinder flow visualization indicated that large part of flow energy dissipated during the intake stroke and energy dissipation was the maximum near the end of the intake stroke.

Light duty vehicle emission standards are getting more stringent than ever before as stipulated by US EPA Tier 2 Standards and LEV III regulations proposed by CARB. The research in this paper sponsored by US DoE is focused towards developing a Tier 2 Bin 2 Emissions compliant light duty pickup truck with class leading fuel economy targets of 22.4 mpg “City” / 34.3 mpg “Highway”. Many advanced technologies comprising both engine and after-treatment systems are essential towards accomplishing this goal. The objective of this paper would be to discuss key engine technology enablers that will help in achieving the target emission levels and fuel economy. Several enabling technologies comprising air-handling, fuel system and base engine design requirements will be discussed in this paper highlighting both experimental and analytical evaluations.

Valve seat inserts (VSI) are installed in cylinder heads to provide a seating surface for poppet valves. Insert material is more heat and wear resistant than the base cylinder head material and hence it makes them better suited for valve seating and improved engine durability. Also use of inserts permits easier repair or rebuild of cylinder heads as only the wear surfaces need to be replaced. Desirable performance characteristics are appropriate sealing, heat-transfer and minimizing valve’s seating face to VSI wear and undesired outputs include valve seat dropping and cracking. With the downsizing trend of diesel engines, it leads to increasing power density and therefore higher cylinder pressure and temperatures. Hence the engine components are getting exposed to more severe loadings and hence to damage modes, which were heretofore not experienced. Among such possible damage modes are insert’s yielding and corresponding press-fit loss leading to either it’s cracking or drop-out.

Performance of a Current generation catalytic converter using Pd/Rh (10:1) as binary catalyst impeded on an ultra thin ceramic substrate and alumina wash coat is modeled for performance prediction and parametric optimization. Kinetic rates for the catalyst are reduced after conducting series of experiments on a passenger car engine. A new concept in mass transfer coefficient is introduced for improving accuracy of the model prediction. In order to take care of the precious metal resources and to become independent of precious metal price fluctuation, a new pattern of loading of precious metal is suggested for optimum performance and metal savings about 46 percent was observed. Experimental investigations were carried out to validate the established kinetic rates over a wide range operation of the engine and for the model validation. Satisfactory agreements are observed for the model prediction and experimental results.

Current production heavy duty diesel engines have a brake thermal efficiency (BTE) between 43-46% [1]. In partnership with the United States Department of Energy (DOE) as part of the Supertruck 2 program, Cummins has undertaken a research program to develop a new heavy-duty diesel engine designed to deliver greater than 50% BTE without the use of waste heat recovery. A system level optimization focused on: increased compression ratio, higher injection rate, carefully matched highly efficient turbocharging, variable lube oil pump, variable cooling components, and low restriction after treatment designed to deliver 50% BTE at a target development point. This work will also illustrate the system level planning and understanding of interactions required to allow that same 50% BTE heavy duty diesel engine to be integrated with a waste heat recovery (WHR) system to deliver system level efficiency of 55% BTE at a single point.

Control and elimination of mobil-source particulate matter (PM) emissions is of increasing interest to engineers and scientists as regulators in industrialized countries promulgate lower emission levels in diesel engines. Relative to their gasoline engine counterparts, today's diesel engines, in general, still emit a higher mass of PM. While strictly speaking, this PM is an agglomeration of organic and inorganic particles, the predominant component is carbon and is commonly referred to as “soot”. For mobil-source PM control, one of the current preferred technologies is the ceramic closed-cell monolith Diesel Particulate Filter (DPF). Ideally, DPFs accumulate and store PM during low speed/temperature engine operation and burn the accumulated PM during high speed/temperature operation.

The influence of big-end bore fretting on connecting rod fatigue fracture is investigated. A finite element model, including rod-bearing contact interaction, is developed to simulate a fatigue test rig where the connecting rod is subjected to an alternating uniaxial load. Comparison of the model results with a rod fracture from the fatigue rig shows good correlation between the fracture location and the peak ‘Ruiz’ criterion, rather than the peak tensile stress location, indicating the potential of fretting to initiate a fatigue fracture and the usefulness of the ‘Ruiz’ criterion as a measure of location and severity. The model is extended to simulate a full engine cycle using pressure loads from a bearing EHL analysis. A fretting map and a ‘Ruiz’ criterion map are developed for the full engine cycle, giving an indication of a safe ‘Ruiz’ level from an existing engine which has been in service for more than 5 years.

Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.

The use of alcohol-gasoline blends enables the favorable features of alcohols to be utilized in spark ignition (SI) engines while avoiding the shortcomings of their application as straight fuels. Eucalyptus and orange oils possess high octane values and are also good potential alternative fuels for SI engines. The high octane value of these fuels can enhance the octane value of the fuel when it is blended with low-octane gasoline. In the present work, 20 percent by volume of orange oil, eucalyptus oil, methanol and ethanol were blended separately with gasoline, and the performance, combustion and exhaust emission characteristics were evaluated at two different compression ratios. The phase separation problems arising from the alcohol-gasoline blends were minimized by adding eucalyptus oil as a co-solvent. Test results indicate that the compression ratio can be raised from 7.4 to 9 without any detrimental effect, due to the higher octane rating of the fuel blends.

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

The effects of fuel composition and engine operating parameters on high-pressure, direct injection gasoline (DIG) injector plugging and deposit formation have been studied. The engine used was a conventional dual-sparkplug, 2.2-liter Nissan engine modified for direct injection using one of the spark plug holes. The engine was run under 20% rich conditions to accelerate deposit formation. A ten-fuel test matrix was designed around T90, sulfur level, and olefin levels indicated in the European gasoline specifications for year 2000. The gasolines, containing no detergents, were formulated using refinery stream blends to match the specified targets. Injector flow loss was monitored by fuel flow to the engine and monitoring oxygen sensors on each of the four cylinders. The impact of fuel composition on deposit formation and injector plugging is discussed. Injector flow loss was strongly influenced by injector tip temperature.

This paper presents the findings of some fundamental characterisation of the deposits that form on the injectors of an air-assisted DISI automotive engine, including the effect of these deposits on engine performance when operated in different combustion modes, with varying fuel composition and additive content. A root cause analysis was undertaken, including an assessment of injector temperature and deposit chemistry. Fuels from a matrix designed around the European year 2000 gasoline specifications for T90, olefin and aromatic levels were used to study the effect of fuel composition on deposit formation. Two commercial gasoline detergent additives, of different chemistries, were used to investigate the impact on deposit formation. The results of the fuels study and deposit analysis are consistent with published theories concerning fuel composition impact on combustion chamber deposit (CCD).

The influence of various diesel fuel properties on the steady state emissions and performance of a Cummins light-duty (ISB) engine modified for single cylinder operation has been studied at the mid-load “cruise” operating condition. Designed experiments involving independent manipulation of both fuel properties and engine control parameters have been used to build statistical engine response models. The models were then applied to optimize for the minimum fuel consumption subject to specific constraints on emissions and mechanical limits and also to estimate the optimum engine control parameter settings and fuel properties. The study reveals that under the high EGR, diffusion-burn dominated conditions encountered during the experiments, NOx is impacted by cetane number and the distillation characteristics. Lower T50 (mid-distillation temperature) resulted in simultaneous reductions in both NOx and smoke, and higher cetane number provided an additional small NOx benefit.