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A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

To meet the challenge of future deep space programs an accurate and efficient engineering code for analyzing the shielding requirements against high-energy galactic heavy radiations is needed. Such engineering design codes require establishing validation processes using laboratory ion beams and space flight measurements in realistic geometries. In consequence, a new version of the HZETRN code capable of simulating HZE ions with either laboratory or space boundary conditions is currently under development. The new code, GRNTRN, is based on a Green's function approach to the solution of Boltzmann's transport equation and like its predecessor is deterministic in nature. Code validation in the laboratory environment is addressed by showing that GRNTRN accurately predicts energy loss spectra as measured by solid-state detectors in ion beam experiments.

A new life support approach is proposed for use on the International Space Station (ISS). This involves advanced technologies for water recovery and air revitalization, tested at the Johnson Space Center (JSC), including bioprocessing, reverse-osmosis and distillation, low power carbon dioxide removal, non-expendable trace contaminant control, and carbon dioxide reduction.

The US Army uses a light tactical High-Mobility Multi-Purpose Wheeled Vehicle (HMMWV) which, due to the amount of armor added, requires air conditioning to keep its occupants comfortable. The current system uses R134a in a dual evaporator, remote-mounted condenser, engine-driven compressor system. This vehicle has been adapted to use an environmentally friendly refrigerant (carbon dioxide) to provide performance, efficiency, comfort and logistical benefits to the Army. The unusual thermal heat management issues and the fact that the vehicle is required to operate under extreme ambient conditions have made the project extremely challenging. This paper is a continuation of work presented at the SAE Alternate Refrigerants Symposium held in Phoenix last June [1].

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

In-cylinder concentrations of nitric oxide (NO) in a diesel engine were studied using a laser-induced fluorescence (LIF) technique that employs two-photon excitation. Two-photon NO LIF images were acquired during the expansion and exhaust portions of the engine cycle providing useful NO fluorescence signal levels from 60° after top dead center through the end of the exhaust stroke. The engine was fueled with the oxygenated compound diethylene glycol diethyl ether to minimize soot within the combustion chamber. Results of the two-photon NO LIF technique from the exhaust portion of the cycle were compared with chemiluminescence NO exhaust-gas measurements over a range of engine loads from 1.4 to 16 bar gross indicated mean effective pressure. The overall trend of the two-photon NO LIF signal showed good qualitative agreement with the NO exhaust-gas measurements.

Due to its high efficiency and superior durability the diesel engine is again becoming a prime candidate for future light-duty vehicle applications within the United States. While in Europe the overall diesel share exceeds 40%, the current diesel share in the U.S. is 1%. Despite the current situation and the very stringent Tier 2 emission standards, efforts are being made to introduce the diesel engine back into the U.S. market. In order to succeed, these vehicles have to comply with emissions standards over a 120,000 miles distance while maintaining their excellent fuel economy. The availability of technologies such as high-pressure common-rail fuel systems, low sulfur diesel fuel, NOx adsorber catalysts (NAC), and diesel particle filters (DPFs) allow the development of powertrain systems that have the potential to comply with the light-duty Tier 2 emission requirements. In support of this, the U.S.

A thermal analysis of the compressible carbon dioxide (CO2) flow for the Portable Fire Extinguisher (PFE) system has been performed. A SINDA/FLUINT model has been developed for this analysis. The model includes the PFE tank and the Temporary Sleep Station (TeSS) nozzle, and both have an initial temperature of 72 °F. In order to investigate the thermal effect on the nozzle due to discharging CO2, the PFE TeSS nozzle pipe has been divided into three segments. This model also includes heat transfer predictions for PFE tank inner and outer wall surfaces. The simulation results show that the CO2 discharge rates and component wall temperatures fall within the requirements for the PFE system. The simulation results also indicate that after 50 seconds, the remaining CO2 in the tank may be near the triple point (gas, liquid and solid) state and, therefore, restricts the flow.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

There is a possibility that trace contaminants in the Shuttle Orbiter cabin atmosphere may chemically react with amine beads found in the Regenerative Carbon Dioxide Removal System and degrade system performance. Two contaminant compounds were exposed to the amine beads, and performance changes were measured. Acetone was tested because it is sometimes found in small but appreciable quantities in the cabin, and it has chemical properties that make it a potential poison. Halon 1301 was tested because it is the fire extinguishant, and a discharge of a Halon canister would trigger high concentrations in the cabin. Acetone was shown to be weakly and reversibly adsorbed. It does not poison the bed, and the RCRS was shown to remove small quantities of acetone. Halon was shown to be inert to the amine. It does not poison the RCRS, and is not removed by the RCRS.

Ignition location is one of the important factors that affect the thermal efficiency, exhaust emissions and knock sensitivity in premixed-charge ignition engines. However, the ignition initiation locations of pre-chamber generated turbulent jet ignition, which is a promising ignition enhancement method, are not clearly understood due to the complex physics behind it. Motivated by this, the ignition initiation location of a transient turbulent jet in a constant volume combustor is analyzed by the use of computational fluid dynamics (CFD) simulations. In the CFD simulations of this work, commercial codes KIVA-3 V release 2 and an in-house-developed chemical solver with a detailed mechanism for H2/air mixtures are used. Comparisons are performed between simulated and experimental ignition initiation locations, and they agree well with one another. A detailed parametric study of the influence of in-cylinder temperature on the ignition initiation location is also performed.

Research into increased capacity solid amine sorbents has found a candidate (SA9T) that will provide enough increase in cyclic carbon dioxide removal capacity to produce a fully redundant Regenerative Carbon Dioxide Removal System (RCRS). This system will eliminate the need for large quantities of backup LiOH, thus gaining critical storage space on board the shuttle orbiter. This new sorbent has shown an ability to package two fully redundant (four) sorbent beds together with their respective valves, fans and plumbing to create two operationally independent systems. The increase in CO2 removal capacity of the new sorbent will allow these two systems to fit within the envelope presently used by the RCRS. This paper reports on the sub-scale amine testing performed in support of the development effort. In addition, this paper will provide a preliminary design schematic of a fully redundant RCRS.

This paper summarizes the Next Generation Natural Gas Vehicle (NG-NGV) Program that is led by the U.S. Department Of Energy's (DOE's) Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of this program is to develop and implement one Class 3-6 compressed natural gas (CNG) prototype vehicle and one Class 7-8 liquefied natural gas (LNG) prototype vehicle in the 2004 to 2007 timeframe. OHVT intends for these vehicles to have 0.5 g/bhp-hr or lower emissions of oxides of nitrogen (NOx) by 2004 and 0.2 g/bhp-hr or lower NOx by 2007. These vehicles will also have particulate matter (PM) emissions of 0.01 g/bhp-hr or lower by 2004. In addition to ambitious emissions goals, these vehicles will target life-cycle economics that are compatible with their conventionally fueled counterparts.

This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.

This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.

Long-duration missions in space will require regenerative air revitalization processes. Human testing of these regenerative processes is necessary to provide focus to the system development process and to provide realistic metabolic and hygiene inputs. To this end, the Lyndon B. Johnson Space Center (JSC), under the sponsorship of NASA Headquarters Office of Life and Microgravity Sciences and Applications, is implementing an Early Human Testing (EHT) Project. As part of this project, an integrated physicochemical Air Revitalization System (ARS) is being developed and tested in JSC's Life Support Systems Integration Facility (LSSIF). The components of the ARS include a Four-Bed Molecular Sieve (4BMS) Subsystem for carbon dioxide (CO2) removal, a Sabatier CO2 Reduction Subsystem (CRS), and a Solid Polymer Electrolyte (SPE)™ Oxygen Generation Subsystem (OGS). A Trace Contaminant Control Subsystem (TCCS) will be incorporated at a later date.

In a crewed spacecraft environment, atmospheric carbon dioxide (CO2) and moisture control are crucial. Hamilton Sundstrand has developed a stable and efficient amine-based CO2 and water vapor sorbent, SA9T, that is well suited for use in a spacecraft environment. The sorbent is efficiently packaged in pressure-swing regenerable beds that are thermally linked to improve removal efficiency and minimize vehicle thermal loads. Flows are all controlled with a single spool valve. This technology has been baselined for the new Orion spacecraft. However, more data was needed on the operational characteristics of the package in a simulated spacecraft environment. A unit was therefore tested with simulated metabolic loads in a closed chamber at Johnson Space Center during the last third of 2006. Tests were run at a variety of cabin temperatures and with a range of operating conditions varying cycle time, vacuum pressure, air flow rate, and crew activity levels.

Biodiesel is a widely used biofuel in diesel engines, which is of particular interest as a renewable fuel because it possesses the similar properties as the diesel fuel. The pure soybean biodiesel was tested in an optical constant volume combustion chamber using natural flame luminosity and forward illumination light extinction (FILE) methods to explore the combustion process and soot distribution at various ambient temperatures (800 K and 1000 K) and oxygen concentrations (21%, 16%, 10.5%). Results indicated that, with a lower ambient temperature, the autoignition delay became longer for all three oxygen concentrations and more ambient air was entrained by spray jet and more fuel was burnt by premixed combustion. With less ambient oxygen concentration, the heat release rate showed not only a longer ignition delay but also longer combustion duration.

An optically accessible single-cylinder high-speed direct-injection (HSDI) Diesel engine equipped with a Bosch common rail injection system was used to study the spray and combustion processes for European low sulfur diesel, bio-diesel, and their blends at different blending ratio. Influences of injection timing and fuel type on liquid fuel evolution and combustion characteristics were investigated under similar loads. The in-cylinder pressure was measured and the heat release rate was calculated. High-speed Mie-scattering technique was employed to visualize the liquid distribution and evolution. High-speed combustion video was also captured for all the studied cases using the same frame rate. NOx emissions were measured in the exhaust pipe. The experimental results indicated that for all of the conditions the heat release rate was dominated by a premixed combustion pattern and the heat release rate peak became smaller with injection timing retardation for all test fuels.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).