Search Results

The influence of the small amounts (1-3%) of the additive di-tertiary butyl peroxide (DTBP) on the combustion event of Homogeneous Charge Compression Ignition (HCCI) engines was investigated using engine experiments, numerical modeling, and carbon-14 isotope tracing. DTBP was added to neat ethanol and diethyl ether (DEE) in ethanol fuel blends for a range of combustion timings and engine loads. The addition of DTBP to the fuel advanced combustion timing in each instance, with the DEE-in-ethanol mixture advancing more than the ethanol alone. A numerical model reproduced the experimental results. Carbon-14 isotope tracing showed that more ethanol burns to completion in DEE-in-ethanol blends with a DTBP additive when compared to results for DEE-in-ethanol without the additive. However, the addition of DTBP did not elongate the heat release in either case.

The potential for catalytically enhanced ignition in low-heat rejection Diesel engines has been experimentally studied under engine simulated conditions in a high pressure chemical flow reactor. Results are presented for propane oxidation on platinum at 6 and 10 atmospheres, at temperatures from 800K to 1050K, and at equivalence ratios from 0.5 to 4.0. For turbulent transport rates which are typical of those in an engine, as much as 20% of the fuel was found to react on the catalyst before the onset of the gas-phase ignition reactions. Depending on the adiabaticity of the combustion chamber walls, this could lead to significant thermal enhancement of the gas-phase ignition process. Evidence of chemical enhancement was also observed, at 10 atm under very fuel rich conditions, in terms of a change in the concentration and distribution of the hydrocarbon intermediate species. Possible mechanisms for the observed chemical enhancement due to surface generated species are discussed.

We have conducted a detailed numerical analysis of HCCI engine operation at low loads to investigate the sources of HC and CO emissions and the associated combustion inefficiencies. Engine performance and emissions are evaluated as fueling is reduced from typical HCCI conditions, with an equivalence ratio ϕ = 0.26 to very low loads (ϕ = 0.04). Calculations are conducted using a segregated multi-zone methodology and a detailed chemical kinetic mechanism for iso-octane with 859 chemical species. The computational results agree very well with recent experimental results. Pressure traces, heat release rates, burn duration, combustion efficiency and emissions of hydrocarbon, oxygenated hydrocarbon, and carbon monoxide are generally well predicted for the whole range of equivalence ratios. The computational model also shows where the pollutants originate within the combustion chamber, thereby explaining the changes in the HC and CO emissions as a function of equivalence ratio.

The application of planar laser-induced Rayleigh scattering for quantitative 2-D measurements of vapor-phase fuel concentration in the main combustion zone of a direct-injection Diesel engine has been explored, developed and demonstrated. All studies were conducted in an optically accessible direct-injection Diesel engine of the “heavy-duty” size class at 1200 rpm and motored TDC conditions which were typical of the production version of this engine. First, this study verifies that beyond 27 mm from the injector all the fuel is vapor phase. This was done by investigating the Diesel jet under high magnification using 2-D elastic scatter imaging and subsequently evaluating the signal intensities from the droplets and other interfering particles (Mie scattering) and the vapor (Rayleigh scattering).

A multi-zone model has been developed that accurately predicts HCCI combustion and emissions. The multi-zone methodology is based on the observation that turbulence does not play a direct role on HCCI combustion. Instead, chemical kinetics dominates the process, with hotter zones reacting first, and then colder zones reacting in rapid succession. Here, the multi-zone model has been applied to analyze the effect of piston crevice geometry on HCCI combustion and emissions. Three different pistons of varying crevice size were analyzed. Crevice sizes were 0.26, 1.3 and 2.1 mm, while a constant compression ratio was maintained (17:1). The results show that the multi-zone model can predict pressure traces and heat release rates with good accuracy. Combustion efficiency is also predicted with good accuracy for all cases, with a maximum difference of 5% between experimental and numerical results.

This paper investigates flow and combustion in a full-cycle simulation of a four-stroke, three-valve HCCI engine by visualizing the flow with pathlines. Pathlines trace massless particles in a transient flow field. In addition to visualization, pathlines are used here to trace the history, or evolution, of flow fields and species. In this study evolution is followed from the intake port through combustion. Pathline analysis follows packets of intake charge in time and space from induction through combustion. The local scalar fields traversed by the individual packets in terms of velocity magnitude, turbulence, species concentration and temperatures are extracted from the simulation results. The results show how the intake event establishes local chemical and thermal environments in-cylinder and how the species respond (chemically react) to the local field.

Enhancement of methanol combustion in a direct injected Diesel engine using catalytically coated glow plugs was examined for platinum and palladium catalysts and compared to a non-catalytic baseline case. Experiments were performed for 6 and 10 brake Kilowatts (bKW) at 2500 rpm. Comparisons were made based on combustion, performance, and emissions including carbon monoxide (CO), oxides of nitrogen (NOx), unburned hydrocarbons (UHC), unburned methanol (UBM), and aldehydes. Results show a decrease in glow plug temperature of 100 K is achievable using platinum catalysts, and 150 K for palladium. Furthermore, the palladium catalyst was found to provide better combustion characteristics than the platinum catalyst. Also, the use of both catalysts produced lower aldehyde emissions, and the palladium reduced NOx emissions as well. However, unburned methanol increased for both catalytic glow plugs with respect to the non-catalytic case.

Multi-zone CFD simulations with detailed kinetics were used to model iso-octane HCCI experiments performed on a single-cylinder research engine. The modeling goals were to validate the method (multi-zone combustion modeling) and the reaction mechanism (LLNL 857 species iso-octane) by comparing model results to detailed exhaust speciation data, which was obtained with gas chromatography. The model is compared to experiments run at 1200 RPM and 1.35 bar boost pressure over an equivalence ratio range from 0.08 to 0.28. Fuel was introduced far upstream to ensure fuel and air homogeneity prior to entering the 13.8:1 compression ratio, shallow-bowl combustion chamber of this 4-stroke engine. The CFD grid incorporated a very detailed representation of the crevices, including the top-land ring crevice and head-gasket crevice. The ring crevice is resolved all the way into the ring pocket volume. The detailed grid was required to capture regions where emission species are formed and retained.

Homogenous Charge Compression Ignition (HCCI) is a new engine technology with fundamental differences over conventional engines. HCCI engines are intrinsically fuel flexible and can run on low-grade fuels as long as the fuel can be heated to the point of ignition. In particular, HCCI engines can run on “wet ethanol:” ethanol-in-water mixtures with high concentration of water, such as the high water content ethanol-in-water mixture that results from fermentation of corn mash. Considering that much of the energy required for processing fermented ethanol is spent in distillation and dehydration, direct use of wet ethanol in HCCI engines considerably shifts the energy balance in favor of ethanol.

Homogeneous charge compression ignition (HCCI) is a new combustion technology that may develop as an alternative to diesel engines with high efficiency and low NOx and particulate matter emissions. This paper describes the HCCI research activities being currently pursued at Lawrence Livermore National Laboratory and at the University of California Berkeley. Current activities include analysis as well as experimental work. On analysis, we have developed two powerful tools: a single zone model and a multi-zone model. The single zone model has proven very successful in predicting start of combustion and providing reasonable estimates for peak cylinder pressure, indicated efficiency and NOx emissions. This model is being applied to develop detailed engine performance maps and control strategies, and to analyze the problem of engine startability. The multi-zone model is capable of very accurate predictions of the combustion process, including HC and CO emissions.

To facilitate the growing interest in hydrogen combustion for internal combustion engines, computer models are being developed to simulate gaseous fuel injection, air entrainment and the ensuing combustion. This paper introduces a new method for modeling the injection and air entrainment processes for gaseous fuels. Modeling combustion is not covered in this paper. The injection model uses a gaseous sphere injection methodology, similar to liquid droplet injection techniques used for liquid fuel injection. In this paper, the model concept is introduced and model results are compared with correctly- and under-expanded experimental data.

The objective of this research was to characterize the effects of fuel component volatility on gasoline direct injection (GDI) engine cold start. Three different fuel components, representing gasoline light end, mid-point and heavy end components, were used to form three fuel blends of different volatility. Performance tests and in-cylinder fuel distribution imaging tests using these fuel blends were carried out in a firing single-cylinder optically-accessible engine following a simulated cold start test schedule. Performance results, based on in-cylinder pressure and engine-out hydrocarbon measurements, during the initial transient phase of GDI cold start showed significantly degraded performance with the low volatility fuel blend, while the high volatility blend showed slightly improved performance. Neither the low nor high volatility fuel, however, showed a discernable effect on the quasi-steady state cold start performance.

The effects of reduced fuel injection pressure on the cold start performance of a GDI engine have been studied in a single-cylinder, optically-accessible research engine. Two Delphi Automotive Systems DI-G injectors, with included spray cone angles of 60° and 80° respectively, were studied. Both injectors are designed to operate at a nominal fuel line pressure of 10 MPa. For the study they were operated at several fuel feed pressures between 10 MPa and 2 MPa. Two start of injection timings (50° and 100° ATDC) were examined. Cold start performance was characterized by measurements of the GIMEP, COV of GIMEP, and total engine out UHCs. Simultaneous Planar Laser Induced Fluorescence (PLIF) and Mie Scattering images of the fuel spray were used to observe spray penetration, mixing, and in-cylinder fuel distribution throughout the intake and compression strokes. Ultimately these images were used to explain observed performance differences.

We have developed an artificial neural network (ANN) based combustion model and have integrated it into a fluid mechanics code (KIVA3V) to produce a new analysis tool (titled KIVA3V-ANN) that can yield accurate HCCI predictions at very low computational cost. The neural network predicts ignition delay as a function of operating parameters (temperature, pressure, equivalence ratio and residual gas fraction). KIVA3V-ANN keeps track of the time history of the ignition delay during the engine cycle to evaluate the ignition integral and predict ignition for each computational cell. After a cell ignites, chemistry becomes active, and a two-step chemical kinetic mechanism predicts composition and heat generation in the ignited cells. KIVA3V-ANN has been validated by comparison with isooctane HCCI experiments in two different engines.

The effects of intake-generated swirl and tumble on cold start performance have been investigated in a firing single-cylinder Gasoline Direct-Injection (GDI) engine. The engine utilizes a Ford Zetec cylinder head modified for GDI operation and a fused silica cylinder which provides extensive optical access to the combustion chamber. Uniquely designed port-inserts were positioned in the intake ports to generate enhanced swirling or tumbling motion inside the cylinder. Experiments were conducted using a constant speed (∼ 900 rpm) simulated cold start procedure, where the engine is motored for approximately 40 cycles, after which fuel injection and spark ignition commence and continue for 190 cycles and then the engine is stopped. Measurements were made of the various engine temperatures, engine-out total hydrocarbon emissions, and in-cylinder pressure throughout the test period.

Homogeneous Charge Compression Ignition (HCCI) engines are currently of great interest as a future alternative to Diesel and Spark Ignition engines because of HCCI's potential to achieve high efficiency with very low NOx emissions. However, significant technical barriers remain to practical implementation of HCCI engines: difficult-to-control combustion, low power density, rapid pressure rise, and high hydrocarbon and carbon monoxide emissions. To overcome some of these barriers, operational strategies that involve relaxing the constraint of truly “homogeneous” HCCI combustion have been studied. The phrase “Premixed Charge Compression Ignition” or “PCCI” combustion can be used to describe this class of combustion processes, in which combustion occurs similarly to HCCI engines as a non-mixing controlled, chemical kinetics dominated, auto-ignition process, but the fuel, air, and residual gas mixture need not be homogeneous.

We have converted a Caterpillar 3406 natural gas spark ignited engine to HCCI mode and used it as a test bed for demonstrating advanced control methodologies. Converting the engine required modification of most engine systems: piston geometry, starting, fueling, boosting, and (most importantly) controls. We implemented a thermal management system consisting of a recuperator that transfers heat from exhaust to intake gases and a dual intake manifold that permits precise cylinder-by-cylinder ignition control. Advanced control methodologies are used for (1) minimizing cylinder-to-cylinder combustion timing differences caused by small variations in temperature or compression ratio; (2) finding the combustion timing that minimizes fuel consumption; and (3) tuning the controller parameters to improve transient response.

Flame kernel growth and cylinder pressure data were simultaneously obtained from an optically-accessible, square piston, SI engine. Flame kernel growth was measured using simultaneous, orthogonal, Schlieren photography, while cylinder pressure was measured using a piezoelectric pressure transducer. The data were analyzed on a cycle-resolved basis to determine the correlation between cyclic fluctuations in flame kernel growth and cylinder pressure. The engine was operated at 875 RPM with premixed, prevaporized, stoichiometric isooctane in air. The engine, designed with ported intake and exhaust, was fired every tenth cycle to ensure complete scavenging. Tests were conducted with and without nitrogen dilution, while ignition timing was fixed at 25° BTDC. With 0% dilution the percent variation in the maximum cylinder pressure was 8.5%, while with 10% dilution the percent variation increased to 14%.

The effect of chromium oxide (Cr2O3) and partially stabilized zirconia (PSZ) surfaces on the gas-phase ignition of hydrocarbon fuels has been studied in a high pressure chemical flow reactor under low heat-loss Diesel engine simulated conditions. Results are presented for propane and n-hexane fuels at 6 and 10 atmospheres and are compared to previously reported results obtained under similar conditions with platinum surfaces. Thermal enhancement of the gas-phase reactions, as evidenced by the catalytic production of CO and CO2, was found to be negligible for both Cr2O3 and PSZ, where as significant thermal enhancement was observed with platinum. Chemical enhancement of the gas-phase ignition reactions, as evidenced by an increase in the production of intermediate hydrocarbons, was observed under fuel rich conditions with both Cr2O3 and PSZ. Oxygen was shown to be essential in that no change in the intermediate hydrocarbon concentration was observed under pyrolysis conditions.

This paper illustrates the applicability of a sequential fluid mechanics, multi-zone chemical kinetics model to analyze HCCI experimental data for two combustion chamber geometries with different levels of turbulence: a low turbulence disc geometry (flat top piston), and a high turbulence square geometry (piston with a square bowl). The model uses a fluid mechanics code to determine temperature histories in the engine as a function of crank angle. These temperature histories are then fed into a chemical kinetic solver, which determines combustion characteristics for a relatively small number of zones (40). The model makes the assumption that there is no direct linking between turbulence and combustion. The multi-zone model yields good results for both the disc and the square geometries. The model makes good predictions of pressure traces and heat release rates.