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Technical Paper

An Advanced Diesel Fuels Test Program

2001-03-05
2001-01-0150
This paper reports on DaimlerChrysler's participation in the Ad Hoc Diesel Fuels Test Program. This program was initiated by the U.S. Department of Energy and included major U.S. auto makers, major U.S. oil companies, and the Department of Energy. The purpose of this program was to identify diesel fuels and fuel properties that could facilitate the successful use of compression ignition engines in passenger cars and light-duty trucks in the United States at Tier 2 and LEV II tailpipe emissions standards. This portion of the program focused on minimizing engine-out particulates and NOx by using selected fuels, (not a matrix of fuel properties,) in steady state dynamometer tests on a modern, direct injection, common rail diesel engine.
Technical Paper

An Efficient Procedure for Vehicle Thermal Protection Development

2005-04-11
2005-01-1904
Vehicle thermal protection is an important aspect of the overall vehicle development process. It involves optimizing the exhaust system routing and designing heat shields to protect various components that are in near proximity to the exhaust system. Reduced time to market necessitates an efficient process for thermal protection development. A robust procedure that utilizes state of the art CFD simulation techniques proactively during the design phase is described. Simulation allows for early detection of thermal issues and development of countermeasures several months before prototype vehicles are built. Physical testing is only used to verify the thermal protection package rather than to develop heat shields. The new procedure reduces the number of physical tests and results in a robust, efficient methodology.
Technical Paper

Application of Urea SCR to Light-Duty Diesel Vehicles

2001-09-24
2001-01-3623
Diesel vehicles have significant advantages over their gasoline counterparts including a more efficient engine, higher fuel economy, and lower emissions of HC, CO, and CO2. However, NOx control is more difficult on a diesel because of the high O2 concentration in the exhaust, making conventional three-way catalysts ineffective. The most promising technology for continuous NOx reduction onboard diesel vehicles is Selective Catalytic Reduction (SCR) using aqueous urea. Recent work with urea SCR has involved aftertreatment for the 1.2L DIATA common-rail diesel engine. This engine was used in Ford's hybrid-electric vehicle, the Prodigy, which was developed under the PNGV (Partnership for a New Generation of Vehicles) program. An emission control system consisting of a diesel particulate filter followed by an underbody SCR system was used successfully to meet ULEV emission standards (0.2 g/mi NOx, 0.04 g/mi particulate matter (PM)).
Technical Paper

Brake Dynamometer Measurement of Airborne Brake Wear Debris

2002-03-04
2002-01-1280
In order to assess the amount of airborne particulate matter (PM) attributable to vehicle disk brakes, a system was devised for collecting brake wear debris on a laboratory brake dynamometer. The brake dynamometer test hardware was enclosed and vented through a duct in which the airflow was controlled to ensure isokinetic sampling. Two brake dynamometer simulations were implemented: urban driving (low velocity, low g) and the Auto Motor und Sport (AMS, high velocity, high g). These test procedures were performed repeatedly on the brake system hardware of vehicles utilizing three different friction material types: low-metallic, semi-metallic, and non-asbestos organic (NAO). Airborne brake wear was collected on filters and via other airborne PM sampling techniques. Larger, non-airborne wear debris was collected from the wheel, below the brake, and brushed off the hardware. Considering the effect of the wheel, 50-70% of the collected wear debris was airborne PM.
Technical Paper

Characteristics of Direct Injection Gasoline Spray Wall Impingement at Elevated Temperature Conditions

1999-10-25
1999-01-3662
The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and doublespark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray.
Technical Paper

Composition of Clusters Formed by Plasma Discharge in Simulated Engine Exhaust

2000-10-16
2000-01-2967
Previously reported experiments revealed the presence of a small number of clusters or very small particles in the effluent of a nonthermal plasma reactor when treating a simulated engine exhaust mixture. These clusters are smaller than 7 nm. The quantity of clusters is orders of magnitude smaller than the particulate diesel or gasoline engine exhaust typically contains. In this report, we describe further experiments designed to determine the chemical composition of the clusters. Clusters were collected on the surface of a silicon substrate by exposing it to the effluent flow for extended time periods. The resulting deposits were analyzed by high mass resolution SIMS and by XPS. The SIMS analysis reveals NH4+, CH6N+, SO-, SO2-, SO3- and HSO4- ions. XPS reveals the presence of N and S at binding energies consistent with that of ammonium sulfate.
Technical Paper

Diesel Exhaust Simulator: Design and Application to Plasma Discharge Testing

2003-03-03
2003-01-1184
A diesel fuel and air diffusion flame burner system has been designed for laboratory simulation of diesel exhaust gas. The system consists of mass flow controllers and a fuel pump, and employs several unique design and construction features. It produces particulate emissions with size, number distribution, and morphology similar to diesel exhaust. At the same time, it generates NOx emissions and HC similar to diesel. The system has been applied to test plasma discharges. Different design discharge devices have been tested, with results indicating the importance of testing devices with soot and moisture. Both packed bed reactor and flat plate dielectric barrier discharge systems remove some soot from the gas, but the designs tested are susceptible to soot fouling and related electrical failures. The burner is simple and stable, and is suitable for development and aging of plasma and catalysts systems in the laboratory environment.
Technical Paper

Effects of Port-Injection Timing and Fuel Droplet Size on Total and Speciated Exhaust Hydrocarbon Emissions

1993-03-01
930711
The requirement of reducing HC emissions during cold start and improving transient performance has prompted a study of the fuel injection process. Port-fuel-injection with the Intake-valve open using small droplets is a potentially feasible option to achieve the goals. To gain a better understanding of the injection process, the effects of droplet size, injection timing, and coolant temperature on the total and speciated HC emissions were tested In a Single-cylinder engine. It was found that droplet size plays an important role in the total HC emission increase during open-valve injection, especially with cold operation. Large droplets (300 μm SMD) produced a substantial HC increase while small droplets (14 μm SMD) produced no observable increase. Increase In the total HC emissions was always accompanied by an increase in the heavy fuel components in the exhaust gases.
Technical Paper

Exhaust Catalytic Converter Bench Fatigue Test Specification Based on Equivalent Damage

2000-03-06
2000-01-0787
Component bench fatigue testing is a cost-effective way to evaluate the durability of exhaust catalytic converters. A successful bench fatigue test depends on the development of a test specification. The test specification should represent the actual customer duty cycle that the component is exposed to. Based on the concept of equivalent fatigue damage, a systematic approach is presented to obtain the test specification from the acquired road load data. A method based on damage analysis is proposed to determine the effective notch factor, and an empirical relationship is presented to account for the thermal effect on the test specification. The principles and procedures of multiple block testing and constant amplitude testing are also presented.
Technical Paper

Experimental and Modeling Evaluations of a Vacuum-Insulated Catalytic Converter

1999-10-25
1999-01-3678
Vehicle evaluations and model calculations were conducted on a vacuum-insulated catalytic converter (VICC). This converter uses vacuum and a eutectic PCM (phase-change material) to prolong the temperature cool-down time and hence, may keep the converter above catalyst light-off between starts. Tailpipe emissions from a 1992 Tier 0 5.2L van were evaluated after 3hr, 12hr, and 24hr soak periods. After a 12hr soak the HC emissions were reduced by about 55% over the baseline HC emissions; after a 24hr soak the device did not exhibit any benefit in light-off compared to a conventional converter. Cool-down characteristics of this VICC indicated that the catalyst mid-bed temperature was about 180°C after 24hrs. Model calculations of the temperature warm-up were conducted on a VICC converter. Different warm-up profiles within the converter were predicted depending on the initial temperature of the device.
Technical Paper

High Frequency Measurements of Pressure and Temperature Fluctuations in an Automotive Exhaust System During Steady State and Transient Driving Conditions

2001-03-05
2001-01-0227
Environmental concerns have prompted increasingly stringent government legislation regulating automotive fuel economy and emissions. Recent rules not only mandate lower total emissions, but also require on-board diagnostics which monitor the vehicle exhaust systems. In order to satisfy these requirements, new and improved exhaust gas sensors are continually being developed to serve as part of the engine feedback control and emissions monitoring systems. Before we can properly design these new sensors, we must attempt to better understand the harsh environment in which they will operate. In this paper, we examine the high frequency nature of pressure fluctuations found in the exhaust system for both steady state and transient engine operating conditions. We also investigate temperature fluctuations, but restrict these measurements to the sampling environment found in the packaging of a Ford Si-based microcalorimeter.
Technical Paper

Plasma-Catalysis for Diesel Exhaust Treatment: Current State of the Art

2001-03-05
2001-01-0185
Nonthermal plasma discharges in combination with catalysts are being developed for diesel aftertreatment. NOx conversion has been shown over several different catalyst materials. Particulate removal has also been demonstrated. The gas phase chemistry of the plasma discharge is described. The plasma is oxidative. NO is converted to NO2, CH3ONO2 and HNO3. Hydrocarbons are partially oxidized resulting in aldehydes and CO along with various organic species. Soot will oxidize if it is held in the plasma. When HC is present, SO2 is not converted to sulfates. Suitable plasma-catalysts can achieve NOx conversion over 70%, with a wider effective temperature range than non-plasma catalysts. NOx conversion requires HC and O2. Electrical power consumption and required exhaust HC levels increase fuel consumption by several percent. A plasma catalyst system has demonstrated over 90% particulate removal in vehicle exhaust.
Technical Paper

Robust Design of a Catalytic Converter with Material and Manufacturing Variations

2002-10-21
2002-01-2888
A design is robust when the performance targets have been achieved and the effects of variation have been minimized without eliminating the causes of the variation such as manufacturing tolerances, material properties, environmental temperature, humidity, operational wear etc. In recent years several robust design concepts have been introduced in an effort to obtain optimum designs and minimize the variation in the product characteristics [1,2]. In this study, a probabilistic design analysis was performed on a catalytic converter substrate in order to determine the required manufacturing tolerance that results in a robust design. Variation in circularity (roundness) and the ultimate shear stress of the substrate material were considered. The required manufacturing tolerance for a robust design with 1,2 and 3 sigma quality levels was determined. The same manufacturing tolerance for a reliability based design with reliability levels of 85%, 90% and 95% was also determined and compared.
Technical Paper

Turbocharging the Chrysler 2.4L Engine

2003-03-03
2003-01-0410
A turbocharged version of the 2.4L engine has been developed by the Chrysler Group of DaimlerChrysler Corporation. This new engine is derived from the proven 2.4L 4-cylinder, with significant changes to achieve a durable, high performance package for the PT Cruiser vehicle. The package includes an integrated turbocharger / exhaust manifold, oil squirters for piston cooling, and numerous other upgrades to satisfy the demanding performance, emissions, and durability requirements unique to this powertrain. The purpose of this paper is to describe the mechanical changes to the base engine, the unique turbocharger configuration, and the new parts necessary to accommodate the higher output.
Technical Paper

Using Artificial Neural Networks for Representing the Air Flow Rate through a 2.4 Liter VVT Engine

2004-10-25
2004-01-3054
The emerging Variable Valve Timing (VVT) technology complicates the estimation of air flow rate because both intake and exhaust valve timings significantly affect engine's gas exchange and air flow rate. In this paper, we propose to use Artificial Neural Networks (ANN) to model the air flow rate through a 2.4 liter VVT engine with independent intake and exhaust camshaft phasers. The procedure for selecting the network architecture and size is combined with the appropriate training methodology to maximize accuracy and prevent overfitting. After completing the ANN training based on a large set of dynamometer test data, the multi-layer feedforward network demonstrates the ability to represent air flow rate accurately over a wide range of operating conditions. The ANN model is implemented in a vehicle with the same 2.4 L engine using a Rapid Prototype Controller.
Technical Paper

Using Diesel Aftertreatment Models to Guide System Design for Tier II Emission Standards

2002-06-03
2002-01-1868
Ford Motor Company is participating in the Department of Energy's (DOE) Ultra-Clean Transportation Fuels Program with the goal to explore the development of innovative emission control systems for advanced compression-ignition direct-injection (CIDI) transportation engines. CIDI (or diesel) engines have the advantages of a potential 40% fuel economy improvement and 20% less CO2 emissions than current gasoline counterparts. To support this goal, Ford plans to demonstrate an exhaust emission control system that provides high efficiency particulate matter (PM) and NOx reduction. Very low sulfur diesel fuel will be used to enable low PM emissions, reduce the fuel economy penalty associated with the emission control system, and increase the long-term durability of the system. The end result will allow vehicles with CIDI engines to be Tier II emissions certified at a minimum cost to the consumer.
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