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The spatial distribution of internal exhaust gas recirculation (EGR) is evaluated in an optically accessible direct injection spark ignition engine using near infrared laser absorption to visualize the distribution of the H2O molecule. The obtained overall internal exhaust gas recirculation compares well to gas-exchange cycle calculations and the spatial distributions are consistent with those measured with inverse LIF. The experimental procedures described in this report are designed to be simple and rapidly implemented without the need to resort to unusual optical components. The necessary spectral data of the selected absorption line is obtained from the HITEMP database and is validated with prior experiments carried out in a reference cell. Laser speckle in the images is effectively reduced using a ballistic diffuser.

In the context of the energy transition, CO2-neutral solutions are of enormous importance for all sectors, but especially for the mobility sector. Hydrogen as an energy carrier has therefore been the focus of research and development for some time. However, the development of hydrogen combustion engines is in many respects still in the conception phase. Automotive system providers and engineering companies in the field of software development and simulation are showing great interest in the topic. In a joint project with the industrial partners Robert Bosch GmbH and AVL Germany, combustion in a H2-DI-engine for use in light-duty vehicles was methodically investigated using the CFD tool AVL FIRE®. The collaboration between Robert Bosch GmbH and the Institute for Mobile Systems (IMS) at Otto von Guericke University Magdeburg has produced a model study in which model approaches for the combustion of hydrogen can be analyzed.

An overview is given on the state of the art of a new catalytic exhaust gas aftertreatment device for diesel engines. The function of a precious metal based, flow-through type diesel oxidation catalyst is explained. Much attention is paid to the durability of the diesel oxidation catalyst and especially to the influence of poisoning elements on the catalytic activity. Detailed data on the interaction of poisoning elements such as sulfur, zinc and phosphorus with the catalytic active sites are given. Finally it is demonstrated that it is possible to meet the stringent emission standards for diesel passenger cars in Europe with a new catalyst generation over 80.000 km AMA aging.

Increasingly stringent tailpipe emissions regulations have prompted renewed interest in catalyst heating technology – where an integrated device supplies supplemental heat to accelerate catalyst ‘light-off’. Bosch and Boysen, following a collaborative multi-year effort, have developed a Rapid Catalyst Heating System (RCH) for gasoline-fueled applications. The RCH system provides upwards of 25 kW of thermal power, greatly enhancing catalyst performance and robustness. Additional benefits include reduction of precious metal loading (versus a ‘PGM-only’ approach) and avoidance of near-engine catalyst placement (limiting the need for enrichment strategies). The following paper provides a technical overview of the Bosch/Boysen (BOB) Rapid Catalyst Heating system – including a detailed review of the system’s architecture, key performance characteristics, and the associated impact on vehicle-level emissions.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

In order to meet future requirements for emission reduction and fuel economy a variety of concepts are available for gasoline engines. In the recent past new pathways have been found using alternative fuels and fuel combinations to establish cost optimized solutions. The presented concept for a SI-engine consists of combined injection of gasoline and hydrogen. A hydrogen enriched gas mixture is being injected additionally to gasoline into the engine manifold. The gas composition represents the output of an onboard gasoline reformer. The simulations and measurements show substantial benefits to improve the combustion process resulting in reduced cold start and warm up emissions and optimized part load operation. The replacement of gasoline by hydrogen-rich gas during engine start leads to zero hydrocarbons in the exhaust gas.

This paper presents advanced planar ZrO2 oxygen sensors being developed at Robert Bosch using a modified tetragonal partially stabilized zirconia (TZP) with high ionic conductivity, high phase stability and high thermo-mechanical strength. Green tape technology combined with highly automated thickfilm techniques allows robust and cost effective manufacturing of those novel sensing elements. Standardization of assembling parts reduces the complexity of the assembly line even in the case of different sensing principles. The sensor family meets the new requirements of modern ULEV strategies like fast light off below 10 s and linear control capability as well as high quality assurance standards. High volume production will start in 1997 for European customers.

The present paper concentrates on the option of catalytic autothermal reforming of gasoline for fuel cell applications. Major parameters of this process are the “Steam to Carbon Ratio” S/C and the air to fuel ratio λ. Computations assuming thermodynamic equilibrium in the autothermal reactor outlet (ATR) were carried out to attain information about their proper choice, as failure in adjusting the parameters within narrow limits has severe consequences on the reforming process. In order to quantify velocity distribution just ahead the catalyst and to evaluate mixing uniformity we designed an ATR featuring an optical access: Thus flow visualization using PIV (Particle Image Velocimetry) and LIF (Laser Induced Fluorescence) technique is possible. Preliminary PIV-results are presented and compared with CFD computations (Computational Fluid D ynamics).

The selective catalytic reduction (SCR) based on urea-water-solution is an effective technique to reduce nitrogen oxides (NOx) emitted from diesel engines. A 3D numerical computer model of the injection of urea-water-solution and their interaction with the exhaust gas flow and exhaust tubing is developed to evaluate different configurations during the development process of such a DeNOx-system. The model accounts for all relevant processes appearing from the injection point to the entrance of the SCR-catalyst: momentum interaction between gas phase and droplets evaporation and thermolysis of droplets hydrolysis of isocyanic acid in gas phase heat transfer between wall and droplets spray/wall-interaction two-component wall film including interaction with gas phase and exhaust tube The single modeling steps are verified with visualizations, patternator measurements, phase-doppler-anemometer results and temperature measurements.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

A new method for the analysis of the gas flow in an internal combustion engine has been developed. It is based on the interactive coupling between commercially available three (STAR-CD) and one dimensional (PROMO) fluid dynamics codes. With this method the detailed transient flow distribution for any engine component of interest can be calculated taking into account the overall gas dynamic interaction with other engine components. The underlying physics and numerics are outlined. A description of the coupling procedure ensuring proper communication between the two computer codes is given. Also addressed is the averaging procedure adopted at the 3D boundaries, including the influence of the 1D/3D interface placement. A first application of this new method is presented, in which the gas flow in a turbo-charged DI-diesel-engine is simulated.

This paper compares 4 different EGR systems by means of simulation in GT-Power. The demands of optimum massive EGR and fresh air rates were based on experimental results. The experimental data were used to calibrate the model and ROHR, in particular. The main aim was to investigate the influence of pumping work on engine and vehicle fuel consumption (thus CO2 production) in different EGR layouts using optimum VG turbine control. These EGR systems differ in the source of pressure drop between the exhaust and intake pipes. Firstly, the engine settings were optimized under steady operation - BSFC was minimized while taking into account both the required EGR rate and fresh air mass flow. Secondly, transient simulations (NEDC cycle) were carried out - a full engine model was used to obtain detailed information on important parameters. The study shows the necessity to use natural pressure differences or renewable pressure losses if reasonable fuel consumption is to be achieved.

Future emission standards for heavy-duty vehicles like Euro 4, Euro 5, US '07 require advanced engine functionality. One contribution to achieve this target is the catalytic reduction of nitrogen oxides by injection of urea water solution to the exhaust gas. An overview on a urea dosing system, also called DENOXTRONIC, is given and a dosing strategy is described.

A fiber optical sensor system was used to detect the local fuel concentration in the vicinity of the spark position in a cylinder of a four-stroke SI production engine. The fuel concentration was determined by the infrared absorption method, which allows crank angle resolved fuel concentration measurements during multiple successive engine cycles. The sensor detects the attenuation of infrared radiation in the 3.4 μm wavelength region due to the infrared vibrational-rotational absorption band of hydrocarbons (HC). The absorption path was integrated in a modified spark plug and a tungsten halide lamp was used as an infrared light source. All investigations were carried out on a four-stroke spark ignition engine with fuel injection into the intake manifold. The measurements were made under starting conditions of the engine, which means a low engine speed. The engine operated with common gasoline (Euro Super) at different air/fuel-ratios.

In this article a new zero-dimensional model is presented for simulating the cylinder pressure in direct injection diesel engines. The model enables the representation of current combustion processes considering multiple injections, high exhaust gas recirculation rates, and turbocharging. In these methods solely cycle-resolved, scalar input variables from the electronic control unit in combination with empirical parameters are required for modeling. The latter are adapted automatically to different engines or modified applications using measured cylinder pressure traces. The verification based on measurements within the entire operating range from engines of different size and type proves the universal applicability and high accuracy of the proposed method.

To meet future CO₂ emissions limits and satisfy the bounds set by exhaust gas legislation reducing the engine displacement while maintaining the power output ("Downsizing") becomes of more and more importance to the SI-engine development process. The total number of cylinders per engine has to be reduced to keep the thermodynamic disadvantages of a small combustion chamber layout as small as possible. Doing so leads to new challenges concerning the mechanical design, the design of the combustion system concept as well as strategies maintaining a satisfying transient torque behavior. To address these challenges a turbocharged 2-cylinder SI engine with gasoline direct injection was designed for research purposes by Weber Motor and Bosch. This paper wants to offer an insight in the design process. The mechanical design as well as the combustion system concept process will be discussed.

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

The study presented in this paper focuses on measures to minimize exhaust gas emissions to meet SULEV targets on a V6 engine by using a cost efficient system configuration. The study consists of three parts. A) In the first stage, the influence of engine management both on raw emissions and catalyst light off performance was optimized. B) Afterwards, the predefined high cell density catalyst system was tested on an engine test bench. In this stage, thermal data and engine out emissions were used for modeling and prediction of light-off performance for further optimized catalyst concepts. C) In the final stage of the program, the emission performance of the test matrix, including high cell density as well as multifunctional single substrate systems, are studied during the FTP cycle. The presented results show the approach to achieve SULEV emission compliance with innovative engine control strategies in combination with a cost effective metallic catalyst design.

General Motors' 3.6L DOHC 4V V6 engine has been upgraded to provide substantial improvements in performance, fuel economy, and emissions for the 2008 model year Cadillac CTS and STS. The fundamental change was a switch from traditional manifold-port fuel injection (MPFI) to spark ignition direct injection (SIDI). Additional modifications include enhanced cylinder head and intake manifold air flow capacities, optimized camshaft profiles, and increased compression ratio. The SIDI fuel system presented the greatest opportunities for system development and optimization in order to maximize improvements in performance, fuel economy, and emissions. In particular, the injector flow rate, orifice geometry, and spray pattern were selected to provide the optimum balance of high power and torque, low fuel consumption, stable combustion, low smoke emissions, and robust tolerance to injector plugging.

The spray development, combustion and emissions in a 1.9L optical, four-cylinder, direct-injection diesel engine were investigated by means of pressure analysis, high-speed cinematography, the two-colour method and exhaust gas analysis for various levels of exhaust gas recirculation (EGR), three EGR temperatures (uncontrolled, hot and cold) and three fuels (diesel, n-heptane and a two-component fuel 7D3N). Engine operating conditions included 1000 rpm/idle and 2000 rpm/2bar with EGR-rates ranging from 0 to 70%. Independent of rate, EGR was found to have a very small effect on spray angle and spray tip penetration but the auto-ignition sites seemed to increase in size and number at higher EGR-rates with associated reduction in the flame luminosity and flame temperature, by, say, 100K at 50% EGR.