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Acid gas removal experiments are carried out in a large bench scale corona radical shower reactor-catalyst hybrid system. A simulated stationary jet engine test cell flue gas is air mixed with NO, SO2 and CH4. NO, NO2 and SO2 concentrations were measured by a Green Line gas analyzer and the trace by-products are determined by Fourier Transform Infra-Red spectroscopy (FTIR). The aerosol particles generated by the acid gases and methane related plasma processes were collected by the electrostatic precipitator operated at !19 kV dc downstream of the reactor. The size of the reactor is (10×30×100 cm) and four pipe with nozzle type radical injectors are placed in series. The corona radical shower electrode used was a 6 mm o.d. tube equipped with 28 hollow electrodes (1.2 mm i.d./1.5 mm o.d.).

Flame ionization detector (FID) analyzers used in emission testing to measure total hydrocarbon emissions have been operating for the last forty years on a fuel mixture of 40% H₂ and 60% helium. These mixtures were selected based on research studies reported in the literature indicating that this particular mixed fuel combination gave the best sensitivity and relative response of the different hydrocarbons present in vehicle exhaust with respect to propane, the calibration gas. During the past few years, it was announced that there is a worldwide shortage of helium which triggered the automotive industry to look for alternatives for helium to be used in FID fuels. Helium which is produced as a byproduct from natural gas fields is non-renewable, expensive, and extremely rare on the earth. Current supply cannot keep up with demand. There are only few natural gas fields producing helium and unless new natural gas fields are found, current helium amounts will continue to dwindle.

The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.

An On-Board Distillation System (OBDS) was developed to extract, from gasoline, a highly volatile crank fuel that allows the reduction of startup fuel enrichment and significant spark retard during cold starts and warm-up. This OBDS was installed on a 2001 Lincoln Navigator to explore the emissions reductions possible on a large vehicle with a large-displacement engine. The fuel and spark calibration of the PCM were modified to exploit the benefits of the OBDS startup fuel. Three series of tests were performed: (1) measurement of the OBDS fuel composition and distillation curve per ASTM D86, (2) measurement of real-time cold start (20 °C) tailpipe hydrocarbon emissions for the first 20 seconds of engine operation, and (3) FTP drive cycles at 20 °C with engine-out and tailpipe emissions of gas-phase species measured each second. Baseline tests were performed using stock PCM calibrations and certification gasoline.

Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEPg) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEPg). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations.

In this study, the compression ratio of a commercial 15L heavy-duty diesel engine was lowered and a split injection strategy was developed to promote partially premixed compression ignition (PPCI) combustion. Various low reactivity gasoline-range fuels were compared with ultra-low-sulfur diesel fuel (ULSD) for steady-state engine performance and emissions. Specially, particulate matter (PM) emissions were examined for their mass, size and number concentrations, and further characterized by organic/elemental carbon analysis, chemical speciation and thermogravimetric analysis. As more fuel-efficient PPCI combustion was promoted, a slight reduction in fuel consumption was observed for all gasoline-range fuels, which also had higher heating values than ULSD. Since mixing-controlled combustion dominated the latter part of the combustion process, hydrocarbon (HC) and carbon monoxide (CO) emissions were only slightly increased with the gasoline-range fuels.

Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. These seven fuels can be divided into groups for examination of the effects of volatility, MTBE, and structure (an aromatic versus an i-alkane). Correlations between the fuel properties and their effects on emissions are presented. Use of steady state tests rather than driving cycles to examine fuel effects on emissions eliminates the complications resulting from accelerations, decelerations, and changes of injection timing but care had to be taken to account for the periodic regenerations of the lean NOx trap/catalyst.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested over the Federal Test Procedure (FTP) driving cycle. Speciated engine-out hydrocarbon emissions were measured. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. One of the blended fuels was CARB Phase 2 reformulated gasoline which was used as the reference fuel. The remaining four blended fuels were made from refinery components to meet specified distillation profiles. The pure hydrocarbon fuels were iso-octane and toluene - an alkane and an aromatic with essentially identical boiling points. The five blended fuels can be grouped to examine the effects of fuel volatility and MTBE. Additionally, correlations were sought between the fuel properties and the Specific Reactivity, the exhaust “toxics”, and the pass-through of unburned fuel species.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.

Hybrid electric vehicles (HEVs) may have key fuel economy and emissions advantages over current conventional vehicles, but they have drawbacks such as frequent engine starts that can slow down market penetration of HEVs. First, the hydrocarbon emissions due to the numerous engine starts would make newly developed HEV powertrains even more demanding on the emission control system. Second, frequent starts may make the engine deteriorate quickly. This study is an attempt to gain a better understanding of the engine start characteristics of two limited-production HEVs (Toyota Prius and Honda Insight). Using fast-response (5 ms) hydrocarbon and NO (nitric oxide) analyzers, the transient emissions were measured in the engine exhaust ports during cold and hot engine starts. On the basis of the experimental findings, several recommendations were made to improve performance and emissions of future HEVs.

The necessity to study spray-wall interaction in internal combustion engines is driven by the evidence that fuel sprays impinge on chamber and piston surfaces resulting in the formation of wall films. This, in turn, may influence the air-fuel mixing and increase the hydrocarbon and particulate matter emissions. This work reports an experimental and numerical study on spray-wall impingement and liquid film formation in a constant volume combustion vessel. Diesel and n-heptane were selected as test fuels and injected from a side-mounted single-hole diesel injector at injection pressures of 120, 150, and 180 MPa on a flat transparent window. Ambient and plate temperatures were set at 423 K, the fuel temperature at 363 K, and the ambient densities at 14.8, 22.8, and 30 kg/m3. Simultaneous Mie scattering and schlieren imaging were carried out in the experiment to perform a visual tracking of the spray-wall interaction process from different perspectives.

The goal of this study was to generate exhaust fast gas data that could be used to identify phenomena that occur before, during, and after stochastic preignition (SPI), also called low-speed preignition (LSPI), events. Crank angle resolved measurement of exhaust hydrocarbons, NO, CO, and CO2 was performed under engine conditions prone to these events. Fuels and engine operating strategies were varied in an attempt to understand similarities and differences in SPI-related behavior that may occur between them. Several different uncommon (typically occurring in less than 1% of engine cycles) features of the fast gas data were identified, and the correlations between them and SPI events were explored. Although the thresholds used to define and identify these observations were arbitrary, they provided a practical means of identifying behavior in the fast gas data and correlating it to SPI occurrence.

In order to further understand the sequence of events leading to stochastic preignition in a spark-ignition engine, a methodology previously developed by the authors was used to evaluate the propensity of a wide range of fuels to establishing propagating flames under conditions representative of those at which stochastic preignition (SPI) occurs. The fuel matrix included single component hydrocarbons, binary mixtures, and real fuel blends. The propensity of each fuel to establish a flame was correlated to multiple fuel properties and shown to exhibit consistent blending behaviors. No single parameter strongly predicted a fuel’s propensity to establish a flame, while multiple reactivity-based parameters exhibited moderate correlation. A two-stage model of the flame establishment process was developed to interpret and explain these results.

Different blends of gasoline range hydrocarbons were investigated to determine the effect of aromatic, naphthenic, and paraffinic content on performance in an autothermal reformer. In addition, we investigated the effects of detergent, antioxidant, and oxygenate additives. These tests indicate that composition effects are minimal at temperatures of 800°C and above, but at lower temperatures or at high gas hourly space velocities (GHSV approaching 100,000 h-1) composition can have a large effect on catalyst performance. Fuels high in aromatic and naphthenic components were more difficult to reform. In addition, additives, such as detergents and oxygenates were shown to decrease reformer performance at lower temperatures.

The high octane rating and more plentiful domestic supply of natural gas make it an excellent alternative to gasoline. Recent studies have shown that using natural gas in dual fuel engines provides one possible strategy for leveraging the advantages of both natural gas and gasoline. In particular, such engines been able to improve overall engine efficiencies and load capacity when they leverage direct injection of the natural gas fuel. While the benefits of these engine concepts are still being explored, differences in fuel composition, combustion process and in-cylinder mixing could lead to dramatically different emissions which can substantially impact the effectiveness of the engine’s exhaust aftertreatment system. In order to explore this topic, this study examined the variations in speciated hydrocarbon emissions which occur for different fuel blends of E10 and compressed natural gas and for different fuel injection strategies on a spark-ignition engine.

In automotive industry it has been a challenge to retain diesel-like thermal efficiency while maintaining low emissions. Numerous studies have shown significant progress in achieving low emissions through the introduction of common-rail injection systems, multiple injections and exhaust gas recirculation and by using a high octane number fuel, like gasoline, to achieve adequate premixing. On the other hand, low temperature combustion strategies, like HCCI and PCCI, have also shown promising results in terms of reducing both NOx and soot emissions simultaneously. With the increasing capacity of computers, multi-dimensional CFD engine modeling enables a reasonably good prediction of combustion characteristics and pollutant emissions, which is the motivation behind the present research. The current research effort presents an optimization study of light-duty compression ignition engine performance, while meeting the emission regulation targets.

Alternative fuels for internal combustion engines have been the subject of numerous studies. The new U.S. Renewable Fuel Standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion gallons by 2022. Because corn-based ethanol will be capped at 15 billion gallons, 21 billion gallons must come from the advanced biofuels category. A potential source to fill the gap may be butanol and its isomers as they possess fuel properties superior to ethanol. Recently, concerns have been raised about emission of currently non-regulated constituents, aldehydes in particular, from alcohol-based fuels. In an effort to assess the relative impact of the U.S. Renewable Fuel Standards on emissions from a modern gasoline engine, both regulated and non-regulated gas constituents were measured from the combustion of three different alcohol isomers in a modern direct-injected (DI) spark ignition (SI) gasoline engine.