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In order to correspond to the exhaust emissions regulations that become severe every year, more advanced engine control becomes necessary. Engine engineers are concerned about the Hydrocarbons (HCs) that flow through the air-intake ports and that are difficult to precisely control. The main sources of the HCs are, the canister purge, PCV, back-flow gas through the intake valves, and Air / Fuel ratio (A/F) may be aggravated when they flow into the combustion chambers. The influences HCs give on the A/F may also grow even greater, which is due to the increasingly stringent EVAP emission regulations, by more effective ventilation in the crankcase, and also by the growth of the VVT-operated angle and timing, respectively. In order to control the A/F more correctly, it is important to estimate the amount of HCs that are difficult to manage, and seek for suitable controls over fuel injection and so on.

A multi-dimensional numerical method for predicting the warm-up characteristic of automobile catalytic converter systems was developed to effectively design catalytic converter systems which achieve low tail pipe emissions with satisfactory packagebility. The features of the method are; (1) consideration of the governing phenomena such as gas flow, heat transfer, and chemical reactions (2) capability of predicting warm-up characteristic for not only the catalytic converters but also the system as a whole during emission test modes such as the USA LA-4 mode. The description of the method is presented. The experimental verifications of the method were conducted to assure the accuracy of it. The effect of design parameters such as electrically heated catalyst (EHC), high loading of noble metal and thin honeycomb wall on warm-up characteristic of the catalyst are analyzed in the paper.

Over the last few decades, in-cylinder visualization using optically accessible engines has been an important tool in the detailed analysis of the in-cylinder phenomena of internal combustion engines. However, most current optically accessible engines are recognized as being limited in terms of their speed and load, because of the fragility of certain components such as the elongated pistons and transparent windows. To overcome these speed and load limits, we developed a new generation of optically accessible engines which extends the operating range up to speeds of 6000 rpm for the SI engine version, and up to in-cylinder pressures of 20 MPa for the CI engine version. The main reason for the speed limitation is the vibration caused by the inertia force arising from the heavy elongated piston, which increases with the square of the engine speed.

In SI engines with port injection system, fuel behavior both in the intake port and in the cylinder has significant influence on the transient A/F characteristics and HC emissions [1]. Therefore, to improve the engine performance, it is very important to understand fuel behavior in the intake port and in the cylinder [2, 3]. This paper describes the following three unique methods to analyze fuel behavior in port injected SI engines and some test results. (1) Observation of fuel behavior in the intake port, using a transparent intake air tube and a strobe synchronized TV-photographic system. (2) Observation of fuel behavior in the cylinder, using a glass cylinder and fluorescent fuel. (3) Measurement of fuel wall wetting in the intake port and in the cylinder, using the engine with electronically controlled hydraulically driven in-take/exhaust valves.

A new proportional collection system for extremely low tailpipe emission measurement in transient conditions has been developed. The new system can continuously sample a minute flow of exhaust gas, at a rate that is proportional to the engine exhaust rate. A zero grade gas dilution technique is utilized to prevent the influence of pollutants in atmospheric air that are the same concentration level as those in the exhaust gas. The system has accuracy within ±5%. For the direct exhaust gas flow meter, a pitot tube type flow meter is utilized as it is simple, heat resistant, sufficiently accurate and has low flow-resistance characteristic. For the collection and dilution controllers, two mass flow controllers (MFC) were adopted. The MFCs' output can be adversely influenced by variation of the specific heat of the sample gas, resulting in flow reporting error.

To meet the requirements for higher horsepower and torque as well as lower fuel consumption and emissions, we have developed a new “Intelligent Variable Valve Timing (VV-i)” system. It gives continuously variable intake cam phasing by up to 60 degrees crank angle (CA) . This system not only increases WOT output by optimizing intake valve closing timing but also reduces fuel consumption and NOx/ HC emissions under part load by increasing intake and exhaust valve overlap on 4 stroke Spark Ignited engines. VVT-i has been applied to optimize a new 3-liter inline 6 engine for higher torque and at the same time better fuel economy with continuous and wide-range cam phasing.

To avoid knocking phenomena, a special crank mechanism for gasoline engine that allowed the piston to move rapidly near TDC (Top Dead Center) was developed and experimentally demonstrated in the previous study. As a result, knocking was successfully mitigated and indicated thermal efficiency was improved [1],[2],[3],[4]. However, performance of the proposed system was evaluated at only limited operating conditions. In the present study, to investigate the effect of piston movement near TDC on combustion characteristics and indicated thermal efficiency and to clarify the knock mitigation mechanism of the proposed method, experimental studies were carried out using a single cylinder engine with a compression ratio of 13.7 at various engine speeds and loads. The special crank mechanism, which allows piston to move rapidly near TDC developed in the previous study, was applied to the test engine with some modification of tooling accuracy.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

The muffler layout in the exhaust system has been optimized for the attenuation of exhaust noise which has not been studied much to this date. As a result, “Exhaust Manifold Muffler” has been developed. This unit is capable of efficiently muffling the primary and secondary componemts of the engine explosion stroke noise. Such task is achieved without deterioration of engine performance by allocating the volume at the junction of the exhaust manifold branch pipes. Acoustic characteristics of “Exhaust Manifold Muffler” have been analyzed by FEM and experimental methods, which have shown that not only does the volume placed at the junction of the exhaust manifold branch pipes work as a conventional muffler, but also prevents the exhaust manifold branch pipes from amplifying exhaust noise. This is the reason why “Exhaust Manifold Muffler” can muffle more efficiently than the conventional muffler.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

In the field of automotive gasoline engines, new products aiming at greater fuel economy and cleaner exhaust gases are under development with the aim of preventing environmental destruction. Severe ignition environments such as lean combustion, stronger charge motion, and large quantities of EGR require ever greater combustion stability. In an effort to meet these requirements, an iridium plug has been developed that achieves high ignitability and long service life through reduction of its diameter, using a highly wear-resistant iridium alloy as the center electrode.(1)(2) Recently, direct injection engines have attracted attention. In stratified combustion, a feature of the direct injection engine, the introduction of rich air-fuel mixtures in the vicinity of the plug ignition region tends to cause carbon fouling. This necessitates plug carbon fouling resistance.

An on-board particulate matter (PM) sensor, consisting of a gas-permeable electrochemical cell with a porous yttria-stabilized zirconia solid oxide electrolyte, was developed to assist the on-board diagnostics (OBD) system of a vehicle. Exhaust is pumped from the anode side to the cathode side and PM deposited on the anode is instantly oxidized by the catalytic effects of the metal component of the electrode at temperatures higher than 350°C. The PM oxidation reaction occurs at the three-phase boundary between the anode, electrolyte and gas phase, and causes a slight change in the bulk average oxygen concentration, which produces electrochemical polarization by the difference in oxygen partial pressures between the anode and cathode. The developed PM sensor has a detection limit of 2 mg/m₃, at which level will enable PM detection in the OBD system according to the EURO VI regulation.

The hydrocarbon adsorption volume character of zeolite was studied. Specifically, the relationship between aluminum content and zeolite hydrocarbon adsorption was investigated, as a potential hydrocarbon adsorbent for exhaust gas. The study also analyzed the relationship between hole diameter and zeolite hydrocarbon adsorption. It was found that hydrocarbon adsorption increased with decreasing aluminum content. Zeolite with a pore size approximately 0.1nm greater than the diameter of hydrocarbon molecules showed the best performance. Zeolites with two different pore sizes were mixed, and succeeded in adsorbing hydrocarbons of carbon number 3 and above. Silver (Ag) ion exchanged zeolite was also used to increase the adsorption of exhaust gas hydrocarbons, including those of carbon number 2.

A new partial strengthening method, TIG (Tungsten Inert Gas) remelting process, for automobile aluminum alloy castings is described. The preferable operating variables to strengthen, and metallurgical-mechanical properties of remelted alloys formed under selected conditions have been investigated. As a result, the mechanical properties such as strength and toughness, and thermal crack resistance of the remelted alloys were improved markedly due to the effects of microstructure refining and cast defects decrement by remelting. So, the application studies for automobile parts to meet the characteristics of this process have been carried out. Consequently, TIG remelting process has been practically used as an available strengthening method for the portion between valve ports of high performance diesel engine cylinder head.

The second generation methanol lean burn system has been developed. The power unit is a new, 4 valve 1.6L in-line four with compact combustion chambers. Lean misfire limit was extended by using a swirl control valve in the intake port which improves combustion under partial load. Lean mixture control is made by using a signal from lean mixture sensor provided in the exhaust manifold. An EGR system has been newly adopted to reduce NOx emissions and a under-floor type catalyst is also used to reduce formaldehyde emission in the cold transient mode in addition to the manifold type catalyst. Permissible excess air ratio range (PEXARR) was defined and used to indicate the potential for reducing vehicle NOx emissions in engine dynamometer tests to optimize compression ratio, valve timing and swirl ratio and to evaluate the effect of the EGR.

The use of exhaust gas recirculation (EGR) in spark ignition engines has been shown to have a number of beneficial effects under specific operating conditions. These include reducing pumping work under part load conditions, reducing NOx emissions and heat losses by lowering peak combustion temperatures, and by reducing the tendency for engine knock (caused by end-gas autoignition) under certain operating regimes. In this study, the effects of EGR addition on knocking combustion are investigated through a combined experimental and modeling approach. The problem is investigated by considering the effects of individual EGR constituents, such as CO2, N2, and H2O, on knock, both individually and combined, and with and without traces species, such as unburned hydrocarbons and NOx. The effects of engine compression ratio and fuel composition on the effectiveness of knock suppression with EGR addition were also investigated.

Squish flow control is well known as a key technology for improving knock limit in spark ignition engines. However, to acquire a sufficient squish area in a four-valve engine is difficult. In order to achieve a maximum effect of knock suppression with a minimum squish area, we have developed, what we call, a Slant Squish Combustion Chamber for new engines. A slant squish compared with a conventional squish produces an effective reverse squish flow in the early expansion stroke, resulting in higher flow velocity and turbulence. Furthermore, flame propagation to squish area and end gas is accelerated. These improvements are considered to suppress the knock phenomenon. Consequently, with a slant squish, a high compression ratio, to achieve low fuel consumption and high engine performance is realized.

The compositions of hydrocarbons in diesel fuel, exhaust gas and particulates were analyzed and the relationships among them were determined. It was found that the compositions of the hydrocarbons in the exhaust gas were almost the same as that of the fuel, and that the hydrocarbons in the particulates corresponded to their heavy fractions. When the engine condition was fixed, both the soluble organic fraction (SOF) and insoluble fraction ( ISF) showed positive correlation coefficients versus HC×R310, where HC denotes the hydrocarbon emission and R310 denotes the backend fraction, as measured by the fraction of fuel boiling above 310°C. On the other hand, when the engine condition was varied, ISF had negative correlation coefficients versus HC×R310, while SOF showed positive correlation coefficients.