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Difficulties in the starting and operation of diesel engines at low temperatures are an important consideration in their design and operation, and in selection of the fuels for their use. Improvements in operation have been achieved primarily through external components of the engine and associated subsystems. A Rapid Compression Machine (RCM) has been modified to operate over a wide range of temperatures (−20°C to 100°C). It is used to isolate the combustion chamber in an environment in which all significant parameters are carefully defined and monitored. The influence of temperature and cetane number on the ignition and combustion processes are analyzed. Examination of the combustion characteristics show that temperature is by far the most influential factor affecting both ignition delay and heat release profiles. Cetane number (ASTM D-613) is not found to be a strong indicator of ignition delay for the conditions investigated.

The U.S. Environmental Protection Agency (EPA) formed a Heavy-Duty Engine Working Group (HDEWG) in the Mobile Sources Technical Advisory Subcommittee in 1995. The goal of the HDEWG was to help define the role of the fuel in meeting the future emissions standards in advanced technology engines (beyond 2004 regulated emissions levels). A three-phase program was developed. This paper presents the results of the statistical analysis of the data collected in the Phase II program. Included is a description of the design of the fuel test matrix, and a listing of the regression equations developed to predict emissions as a function of fuel density, cetane number, monoaromatics, and polyaromatics. Also included is a description of selected analyses of the emissions from a smaller set of fuel data that allowed direct comparison of the effects of natural and boosted cetane number.

In 1995, US Environmental Protection Agency (EPA) formed the Heavy-Duty Engine Working Group (HDEWG). The objective of the group was to assess the role diesel fuel could play in meeting exhaust emission standards proposed for model year 2004+ heavy-duty diesel engines. The group developed a three-phase program to achieve this objective. This paper describes the development of test fuels used in Phase 2 of the EPA HDEWG Program to investigate the effect of fuel properties on heavy-duty diesel engine emissions. It discusses the design of the fuel matrix, reviews the process of test fuel preparation and presents the results of a multi-laboratory fuel analysis program. Fuel properties selected for investigation included density, cetane number, mono- and polyaromatic hydrocarbon content.

In 1997 the US EPA formed a Heavy-Duty Engine Working Group (HDEWG) in the Mobile Sources Technical Advisory Subcommittee to address the questions related to fuel property effects on heavy-duty diesel engine emissions. The Working Group consisted of members from EPA and the oil refining and engine manufacturing industries. The goal of the Working Group was to help define the role of the fuel in meeting the future emissions standards in advanced technology engines (beyond 2004 regulated emissions levels). To meet this objective a three-phase program was developed. Phase I was designed to demonstrate that a prototype engine, located at Southwest Research Institute, represented similar emissions characteristics to that of certain manufacturers prototype engines. Phase II was designed to document the effects of selected fuel properties using a statistically designed fuel matrix in which cetane number, density, and aromatic content and type were the independent variables.

Effects of methyl ester biodiesel fuel blends on NOx emissions are studied experimentally and analytically. A precisely controlled single cylinder diesel engine experiment was conducted to determine the impact of a 20% blend of soy methyl ester biodiesel (B20) on NOx emissions. The data were then used to calibrate KIVA chemical kinetics models which were used to determine how the biodiesel blend affects NOx production during the combustion process. In addition, the impact on the engine control system of the lower specific energy content of biodiesel was determined. Both factors, combustion and controls, must be taken into account when determining the net NOx effect of biodiesel compared to conventional diesel fuel. Because the magnitude and even direction of NOx effect changes with engine load, the NOx effect associated with burning biodiesel blends over a duty cycle depends on the duty cycle average power and fuel cetane number.

An experimental study was conducted on a spark-ignited direct-injection engine burning fuels with different evaporation and autoignition characteristics. The test engine was a single-cylinder Direct-Injection Stratified-Charge (DISC) engine incorporating a combustion process similar to the Texaco Controlled Combustion System. Two fuels were tested and compared with a baseline gasoline fuel: diesel fuel, and gasoline mixed with an ignition improver. The tests were done at low to medium engine loads. Diesel fuel was found to have similar levels of hydrocarbon (HC) emissions as gasoline but had different characteristics. The optimum timing for diesel fuel was retarded from that for gasoline and combustion variability was much less with diesel than with gasoline. Gasoline with a commercial ignition improver normally used to increase the cetane number of diesel fuel was also tested. The effect of changing the autoignition quality of the fuel depended on the injector used.