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A methodology is presented with which aggregate emissions from the in-use automobile population can be calculated for any given calendar year. The data base needed for such a calculation is discussed, and areas in which further research is needed are pointed out. Results of a series of calculations are then presented showing the effect on aggregate emissions of various control strategies. The effects of an inspection/maintenance and retrofit program, different vehicle population growth rates, catalyst deterioration in use, and various schedules of new car emission standards for post-1975 vehicles are presented. It is shown that the rate at which old, higher-polluting vehicles are retired from the in-use vehicle population is the major factor in determining the rate at which aggregate emissions will decrease in the 1970s, with the precise level of post-1975 standards only becoming important in the 1980s.

Passenger cars in the United States continue to incorporate increasing levels of technology and features. However, deployment of technology requires substantial development and time in the automotive sector. Prior analyses indicate that deployment of technology in the automotive sector can be described by a logistic function. These analyses refer to maximum annual growth rates as high as 17% and with developmental times of 10-15 years. However, these technologies vary widely in complexity and function, and span decades in their implementation. This work applies regression with a logistic form to a wide variety of automotive features and technologies and, using secondary regression, identifies broader trends across categories and over time.

This paper reviews the major changes that have occurred in spark-ignition engine design and operation over the last two decades. The automobile air pollution problem, automobile emission standards, and automobile fuel economy standards -- the factors which have and are producing these changes -- are briefly described. The major components in spark-ignition engine emission control systems are outlined, and advances in carburetion, fuel injection, ignition systems, spark retard and exhaust gas recycle strategies, and catalytic converters, are reviewed. The impact of these emission controls on vehicle fuel economy is assessed. The potential for fuel economy improvements in conventional spark-ignition engines is examined, and promising developments in improved engine and vehicle matching are outlined.

A computer simulation of the four-stroke spark-ignition engine cycle has been developed for studies of the effects of variations in engine design and operating parameters on engine performance, efficiency and NO emissions. The simulation computes the flows into and out of the engine, calculates the changes in thermodynamic properties and composition of the unburned and burned gas mixtures within the cylinder through the engine cycle due to work, heat and mass transfers, and follows the kinetics of NO formation and decomposition in the burned gas. The combustion process is specified as an input to the program through use of a normalized rate of mass burning profile. From this information, the simulation computes engine power, fuel consumption and NO emissions. Predictions made with the simulation have been compared with data from a single-cylinder CFR engine over a range of equivalence ratios, spark-timings and compression ratios.

Dilute operation of a SI engine offers attractive performance incentives. Lowered combustion temperatures and changes in the mixture composition inhibit NOx formation and increase the effective value of the ratio of burned gas specific heats, increasing gross indicated efficiency. Additionally, reduced intake manifold throttling minimizes pumping losses, leading to higher net indicated efficiency. These benefits are offset by the reduced combustion speed of dilute fuel-air mixtures, which can lead to high cycle-to-cycle variation and unacceptable engine behavior characteristics. Hydrogen enhancement can suppress the undesirable consequences of dilute operation by accelerating the combustion process, thereby extending the dilution limit. Hydrogen would be produced on-board the vehicle with a gasoline reforming device such as the plasmatron. High dilution at higher loads would necessitate boosting to meet the appropriate engine specific power requirements.

Experiments to study the effects of oxygenated fuels on emissions and combustion were performed in a single-cylinder direct-injection (DI) diesel engine. A matrix of oxygen containing fuels assessed the impact of weight percent oxygen content, oxygenate chemical structure, and oxygenate volatility on emissions. Several oxygenated chemicals were blended with an ultra-low sulfur diesel fuel and evaluated at an equivalent energy release and combustion phasing. Additional experiments investigated the effectiveness of oxygenated fuels at a different engine load, a matched fuel/air equivalence ratio, and blended with a diesel fuel from the Fischer-Tropsch process. Interactions between emissions and critical engine operating parameters were also quantified. A scanning mobility particle sizer (SMPS) was used to evaluate particle size distributions, in addition to particulate matter (PM) filter and oxides of nitrogen (NOx) measurements.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

This vehicle simulation study estimates the fuel economy benefits of an HCCI engine system and assesses the NOx, HC and CO aftertreatment performance required for compliance with emissions regulations on U.S. and European regulatory driving cycles. The four driving cycles considered are the New European Driving Cycle, EPA City Driving Cycle, EPA Highway Driving Cycle, and US06 Driving Cycle. For each driving cycle, the following influences on vehicle fuel economy were examined: power-to-weight ratio, HCCI combustion mode operating range, driving cycle characteristics, requirements for transitions out of HCCI mode when engine speeds and loads are within the HCCI operating range, fuel consumption and emissions penalties for transitions into and out of HCCI mode, aftertreatment system performance and tailpipe emissions regulations.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

A model has been developed which predicts engine-out hydrocarbon (HC) emissions for spark-ignition engines. The model consists of a set of scaling laws that describe the individual processes that contribute to HC emissions. The model inputs are the critical engine design and operating variables. This set of individual process scaling relations was then calibrated using production spark-ignition engine data at a fixed light-load operating point. The data base consisted of engine-out HC emissions from two-valve and four-valve engine designs with variations in spark timing, valve timing, coolant temperature, crevice volume, and EGR, for five different engines. The model was calibrated separately for the three different engines to accommodate differences in engine design details and to determine the relative magnitudes of each of the major sources. A good fit to this database was obtained.

The trade-off between engine operating efficiency and NOx emissions in the prechamber three-valve stratified-charge engine is examined in a series of parametric studies using an improved model developed at M.I.T. (1). Engine geometric, operating, and combustion parameters are varied independently and the effects on brake-specific-fuel-consumption, exhaust temperature and brake-specific-NO observed. Parameters chosen for study are: timing of the start of combustion, overall air-fuel ratio, prechamber air-fuel ratio at the start of combustion, main-chamber combustion duration, prechamber size (prechamber volume and orifice diameter), EGR (in main and prechamber intakes), and load. The results quantify trade-off opportunities amongst these design and operating variables which are available to the engine designer.

This study examines the scaling between engine performance, engine configuration, and engine size and geometry, for modern spark-ignition engines. It focuses especially on design features that impact engine breathing. We also analyze historical trends to illustrate how changes in technology have improved engine performance. Different geometric parameters such as cylinder displacement, piston area, number of cylinders, number of valves per cylinder, bore to stroke ratio, and compression ratio, in appropriate combinations, are correlated to engine performance parameters, namely maximum torque, power and brake mean effective pressure, to determine the relationships or scaling laws that best fit the data. Engine specifications from 1999 model year vehicles sold in the United States were compiled into a database and separated into two-, three-, and four-valves-per-cylinder engine categories.

The development of a cycle simulation model for the jet ignition prechamber stratified charge engine is described. Given the engine geometry, load, speed, air-fuel ratios and pressures and temperatures in the two intakes, flow ratio and a suitable combustion model, the cycle simulation predicts engine indicated efficiency and NO emissions. The relative importance of the parameters required to define the combustion model are then determined, and values for ignition delay and burn angle are obtained by matching predicted and measured pressure-time curves. The variation in combustion parameters with engine operating variables is then examined. Predicted and measured NO emissions are compared, and found to be in reasonable agreement over a wide range of engine operation. The relative contribution of the prechamber NO to total exhaust NO is then examined, and in the absence of EGR, found to be the major source of NO for overall air-fuel ratios leaner than 22:1.

An improved theoretical model that predicts the nitric oxide concentration in the exhaust of a spark-ignition engine has been evaluated over a wide range of fuel-air ratios, percentage of exhaust gas recycled, and engine speed. Experiments were carried out in a standard CFR single-cylinder engine. Comparison of the measured and calculated exhaust nitric oxide concentrations shows good agreement over all operating conditions. It is shown that in lean mixtures, nitric oxide concentrations freeze early in the expansion stroke. For rich mixtures, freezing occurs later after all the charge has been burned and substantial nitric oxide decomposition takes place. In addition, effects of exhaust gas recirculation on flame speed, ignition delay, and cycle-to-cycle pressure variations were evaluated. A simple model relating cycle-to-cycle variations with changes in ignition delay is presented.

A performance model of a Wankel engine is developed which performs a leakage mass balance, accounts for heat transfer and flame quenching, and predicts the mass fraction burned as a function of chamber pressure. Experiments were performed on a production Wankel engine to obtain chamber pressure-time diagrams, and engine performance and emissions data. Model predictions of mass burned, global heat transfer, and hydrocarbon emission gave good agreement with measurements. Predictions of oxides of nitrogen are higher than measurements, especially at low loads. This is thought to be due to the adiabatic core gas assumption in the model. The need for a Wankel boundary layer study is identified.

This paper evaluates how the fuel consumption of the average new U.S. passenger car will be penalized if engine and vehicle improvements continue to be focused on developing bigger, heavier and more powerful automobiles. We quantify a parameter called the Emphasis on Reducing Fuel Consumption (ERFC) and find that there has been little focus on improving fuel consumption in the U.S. over the past twenty years. In contrast, Europe has seen significantly higher ERFC. By raising the ERFC over the next few decades, we can reduce the average U.S. new car's fuel consumption by up to some 40 percent and cut the light-duty vehicle fleet's fuel use by about a quarter. Achieving substantial fuel use reduction will remain a major challenge if automobile size, weight and power continue to dominate.

Measurements were made of exhaust histories of the following species: unburned hydrocarbons (HC), carbon monoxide, carbon dioxide, oxygen, and nitric oxide (NO). The measurements show that the exhaust flow can be divided into two distinct phases: a leading gas low in HC and high in NO followed by a trailing gas high in HC and low in NO. Calculations of time resolved equivalence ratio throughout the exhaust process show no evidence of a stratified combustion. The exhaust mass flow rate is time resolved by forcing the flow to be locally quasi-steady at an orifice placed in the exhaust pipe. The results with the quasi-steady assumption are shown to be consistent with the measurements. Predictions are made of time resolved mass flow rate which compare favorably to the experimental data base. The composition and flow histories provide sufficient information to calculate the time resolved flow rates of the individual species measured.

A prior study (Chon and Heywood, [1]) examined how the design and performance of spark-ignition engines evolved in the United States during the 1980s and 1990s. This paper carries out a similar analysis of trends in basic engine design and performance characteristics over the past decade. Available databases on engine specifications in the U.S., Europe, and Japan were used as the sources of information. Parameters analyzed were maximum torque, power, and speed; number of cylinders and engine configuration, cylinder displacement, bore, stroke, compression ratio; valvetrain configuration, number of valves and their control; port or direct fuel injection; naturally-aspirated or turbocharged engine concepts; spark-ignition and diesel engines. Design features are correlated with these engine’s performance parameters, normalized by engine and cylinder displacement.