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Homogeneous Charge Compression Ignition (HCCI) combustion is a process dominated by chemical kinetics of the fuel-air mixture. The hottest part of the mixture ignites first, and compresses the rest of the charge, which then ignites after a short time lag. Crevices and boundary layers generally remain too cold to react, and result in substantial hydrocarbon and carbon monoxide emissions. Turbulence has little effect on HCCI combustion, and may be most important as a factor in determining temperature gradients and boundary layer thickness inside the cylinder. The importance of thermal gradients inside the cylinder makes it necessary to use an integrated fluid mechanics-chemical kinetics code for accurate predictions of HCCI combustion. However, the use of a fluid mechanics code with detailed chemical kinetics is too computationally intensive for today's computers.

An experimental study of the Homogeneous Charge Compression Ignition (HCCI) combustion process has been conducted by using chemiluminescence imaging. The major intent was to characterize the flame structure and its transient behavior. To achieve this, time resolved images of the naturally emitted light were taken. Emitted light was studied by recording its spectral content and applying different filters to isolate species like OH and CH. Imaging was enabled by a truck-sized engine modified for optical access. An intensified digital camera was used for the imaging. Some imaging was done using a streak-camera, capable of taking eight arbitrarily spaced pictures during a single cycle, thus visualizing the progress of the combustion process. All imaging was done with similar operating conditions and a mixture of n-heptane and iso-octane was used as fuel. Some 20 crank angles before Top Dead Center (TDC), cool flames were found to exist.

This paper illustrates the applicability of a sequential fluid mechanics, multi-zone chemical kinetics model to analyze HCCI experimental data for two combustion chamber geometries with different levels of turbulence: a low turbulence disc geometry (flat top piston), and a high turbulence square geometry (piston with a square bowl). The model uses a fluid mechanics code to determine temperature histories in the engine as a function of crank angle. These temperature histories are then fed into a chemical kinetic solver, which determines combustion characteristics for a relatively small number of zones (40). The model makes the assumption that there is no direct linking between turbulence and combustion. The multi-zone model yields good results for both the disc and the square geometries. The model makes good predictions of pressure traces and heat release rates.

Homogeneous Charge Compression Ignition (HCCI) combustion is limited in maximum load due to high peak pressures and excessive combustion rate. If the rate of combustion can be decreased the load range can be extended. From previous studies it has been shown that by using a deep square bowl in piston geometry the load range can be extended due to decreased heat release rates, pressure rise rates and longer combustion duration compared to a disc shaped combustion chamber. The explanation for the slower combustion was found in the turbulent flow field in the early stages of the intake stroke causing temperature stratifications throughout the charge. With larger temperature differences the combustion will be longer compared to a perfectly mixed charge with less temperature variations. The methods used for finding this explanation were high-speed cycle-resolved chemiluminescence imaging and fuel tracer planar laser induced fluorescence (PLIF), together with large eddy simulations (LES).

In this paper the combustion chamber wall temperature was measured by the use of thermographic phosphor. The temperature was monitored over a large time window covering a load transient. Wall temperature measurement provide helpful information in all engines. This temperature is for example needed when calculating heat losses to the walls. Most important is however the effect of the wall temperature on combustion. The walls can not heat up instantaneously and the slowly increasing wall temperature following a load transient will affect the combustion events sucseeding the transient. The HCCI combustion process is, due to its dependence on chemical kinetics more sensitive to wall temperature than Otto or Diesel engines. In depth knowledge about transient wall temperature could increase the understanding of transient HCCI control. A “black box” state space model was derived which is useful when predicting transient wall temperature.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

Cycle resolved wall temperature measurements have been performed in a one cylinder port injected optical Scania D12 truck engine run in HCCI mode. Point measurements at various locations were made using Laser-Induced Phosphorescence (LIP). Single point measurements with thermographic phosphors utilize the temperature dependancy of the phosphorescence decay time. The phosphorescence peak at 538 nm from the thermographic phosphor La2O2S:Eu was used to determine temperature. A frequency tripled 10 Hz pulsed Nd:YAG laser delivering ultra violet (UV) radiation at 355 nm was used for excitation of the phosphor. Detection in the spectral region 535 - 545 nm was performed every cycle with a photo multiplier tube connected to a 3 GHz oscilloscope. Measurements were made at four points on the cylinder head surface and two points on the outlet and inlet valves respectively. For each location measurements were made at different loads and at different crank angle degrees (CAD).

The potential of a Homogeneous Charge Compression Ignition (HCCI) engine with variable compression ratio has been experimentally investigated. The experiments were carried out in a single cylinder engine, equipped with a modified cylinder head. Altering the position of a secondary piston in the cylinder head enabled a change of the compression ratio. The secondary piston was controlled by a hydraulic system, which was operated from the control room. Dual port injection systems were used, which made it possible to change the ratio of two different fuels with the engine running. By mixing iso-octane with octane number 100 and normal heptane with octane number 0, it was possible to obtain any octane rating between 0 and 100. By using an electrical heater for the inlet air, it was possible to adjust the inlet air temperature to a selected value.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

An interest in measuring ion current in Homogeneous Charge Compression Ignition (HCCI) engines arises when one wants to use a cheaper probe for feedback of the combustion timing than expensive piezo electric pressure transducers. However the location of the ion current probe, in this case a spark plug, is of importance for both signal strength and the crank angle position where the signal is obtained. Different fuels will probably affect the ion current in both signal strength and timing and this is the main interest of this investigation. The measurements were performed on a Scania D12 engine in single cylinder operation and ion current was measured at 7 locations simultaneously. By arranging this setup there was a possibility to investigate if the ion current signals from the different spark plug locations would correlate with the fact that, for this particular engine, the combustion starts at the walls and propagates towards the centre of the combustion chamber.

The use of water injection in a Homogeneous Charge Compression Ignition (HCCI) engine was experimentally investigated. The purpose of this study was to examine whether it is possible to control the ignition timing and slow down the rate of combustion with the use of water injection. The effects of different water flows, air/fuel ratios and inlet pressures were studied for three different fuels, iso-octane, ethanol and natural gas. It is possible to control the ignition timing in a narrow range with the use of water injection, but to the prize of an increase in the already high emissions of unburned hydrocarbons. The CO emission also increased. The NOx emissions, which are very low for HCCI, decreased even more when water injection was applied. The amount of water used was of the magnitude of the fuel flow.

One way to extend the lean burn limit of a natural gas engine is by addition of hydrogen to the primary fuel. This paper presents measurements made on a one cylinder 1.6 liter natural gas engine. Two combustion chambers, one slow and one fast burning, were tested with various amounts of hydrogen (0, 5, 10 and 15 %-vol) added to natural gas. Three operating points were investigated for each combustion chamber and each hydrogen content level; idle, part load (5 bar IMEP) and 13 bar IMEP (simulated turbocharging). Air/fuel ratio was varied between stoichiometric and the lean limit. For each operating point, a range of ignition timings were tested to find maximum brake torque (MBT) and/or knock. Heat-release rate calculations were made in order to assess the influence of hydrogen addition on burn rate. Addition of hydrogen showed an increase in burn rate for both combustion chambers, resulting in more stable combustion close to the lean limit.

The major advantages with Homogeneous Charge Compression Ignition, HCCI, is high efficiency in combination with low NOx-emissions. The major drawback with HCCI is the problem to control the ignition timing over a wide load and speed range. Other drawbacks are the limitation in attainable IMEP and relativly high emissions of unburned hydrocarbons. But the use of Exhaust Gas Recycling (EGR) instead of only air, slows down the rate of combustion and makes it possible to use lower air/fuel ratio, which increases the attainable upper load limit. The influence of mixture quality was therefore experimentally investigated. The effects of different EGR rates, air/fuel ratios and inlet mixture temperatures were studied. The compression ratio was set to 18:1. The fuels used were iso-octane, ethanol and commercially available natural gas. The engine was operated naturally aspirated mode for all tests.

Measurement of ion current signal from HCCI combustion was performed. The aim of the work was to investigate if a measurable ion current signal exists and if it is possible to obtain useful information about the combustion process. Furthermore, influence of mixture quality in terms of air/fuel ratio and EGR on the ion current signal was studied. A conventional spark plug was used as ionization sensor. A DC voltage (85 Volt) was applied across the electrode gap. By measuring the current through the gap the state of the gas can be probed. A comparison between measured pressure and ion current signal was performed, and dynamic models were estimated by using system identification methods. The study shows that an ion current signal can be obtained from HCCI combustion and that the signal level is very sensitive to the fuel/air equivalence ratio.

To reach the very strict Euro VI regulations of PM and NOx for heavy-duty trucks, it will be necessary to apply integrated catalytic solutions for removal of both PM and NOx. The most cost-effective solution would be to base the Euro VI system on Euro IV/V base engines, without EGR, and apply a high efficiency aftertreatment system, able to reduce the NOx from the common 7-8 g/kWh down to the Euro VI level at 0.4 g/kWh. The described system consists of a catalytic configuration, where the SCR catalyst is placed directly downstream of the diesel engine followed by an ammonia slip catalyst (ASC) and diesel injection over an oxidation catalyst (DOC) and a catalyzed diesel particulate filter (cDPF).

Detailed chemical kinetics was implemented in the KIVA-3V multidimensional CFD code to study the combustion process in Homogeneous Charge Compression Ignition (HCCI) engines. The CHEMKIN code was implemented such that the chemistry and flow solutions were coupled. Detailed reaction mechanisms were used to simulate the fuel chemistry of ignition and combustion. Effects of turbulent mixing on the reaction rates were also considered. The model was validated using the experimental data from two modified heavy-duty diesel engines, including a Volvo engine and a Caterpillar engine operated at the HCCI mode. The results show that good levels of agreement were obtained using the present KIVA/CHEMKIN model for a wide range of engine conditions, including various fuels, injection systems, engine speeds, and EGR levels. Ignition timings were predicted well without the need to adjust any kinetic constants.

The present study uses a numerical model to investigate the effects of flow turbulence on premixed iso-octane HCCI engine combustion. Different levels of in-cylinder turbulence are generated by using different piston geometries, namely a disc-shape versus a square-shape bowl. The numerical model is based on the KIVA code which is modified to use CHEMKIN as the chemistry solver. A detailed reaction mechanism is used to simulate the fuel chemistry. It is found that turbulence has significant effects on HCCI combustion. In the current engine setup, the main effect of turbulence is to affect the wall heat transfer, and hence to change the mixture temperature which, in turn, influences the ignition timing and combustion duration. The model also predicts that the combustion duration in the square bowl case is longer than that in the disc piston case which agrees with the measurements.

Interest in ion current sensing for HCCI combustion arises when a feedback signal from some sort of combustion sensor is needed in order to determine the state of the combustion process. A previous study has revealed that ion current sensors in the form of spark plugs can be used instead of expensive piezoelectric transducers for HCCI combustion sensing. Sufficiently high ion current levels were achieved when using relatively rich mixtures diluted with EGR. The study also shows that it is not the actual dilution per se but the actual air/fuel equivalence ratio which is important for the signal level. Conclusions were made that it is possible to obtain information on combustion timing and oscillating wave phenomena from the measurements. However, the study showed that the ion current is local compared to the pressure which is global in the combustion chamber.

To reach the EPA ‘10 and Euro VI strict regulations of PM and NOx for heavy duty trucks it will be necessary to apply integrated catalytic solutions for removal of both PM and NOx. The described system consists of an alternative catalytic configuration where the SCR catalyst is placed downstream of the diesel engine followed by diesel injection over an oxidation catalyst (DOC) and a catalysed diesel particulate filter (cDPF). One of the advantages of this system configuration is that the SCR catalyst in this way is protected from high temperatures during filter regeneration and that the SCR catalyst has the fastest heat up required for good performance in cold test cycles. The SCR catalyst can therefore be of a standard V-based type that is already proven technology for Euro IV and Euro V compliance in Europe. Another advantage is that the DOC and cDPF act as clean-up catalysts for any possible ammonia slip from the SCR catalyst.

Calculations using homogeneous and stochastic reactor models were performed in order to find an explanation to observed properties of NOx HCCI engines. It was found that for moderate NOx levels, N2O reactions play an important role in the NOx formation. Further, the high proportions of NO2 found in from some HCCI engines is due to high temperature inhomogeneities, poor mixing and slow overall combustion. N2O is often emitted from HCCI combustion. The levels of NOx in the exhausts are highly sensitive to temperature; however N2O has a weak negative dependence on temperature. While fuel rich operation naturally leads to high temperatures and thus high NOx levels; once the temperature effects are decoupled the fuel rich conditions themselves has a favorable effect on low-NOx engine operation.