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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.

It has been long established fact that fuel economy is a key driving force of low viscosity gasoline engine oil research and development considered by the original equipment manufacturers (OEMs) and lubricant companies. The development of low viscosity gasoline engine oils should not only focus on fuel economy improvement, but also on the low speed pre-ignition (LSPI) prevention property. In previous LSPI prevention literatures, the necessity of applying Ca/Mg-based detergents system in the engine oil formulations was proposed. In this paper, we adopted a specific Group III base oil containing Ca-salicylate detergent, borated dispersant, Mo-DTC in the formulation and investigated the various effects of Mg-salicylate and Mg-sulfonate on the performance of engine oil. It was found that Mg-sulfonate showed a significant detrimental impact on silicone rubber compatibility while the influence from Mg-salicylate remains acceptable.

A 1.8L turbocharged diesel engine valvetrain friction was investigated, and the effectiveness of using a solid film lubricant (SFL) coating in reducing friction was determined throughout the operable speed range. This valvetrain design features direct acting mechanical bucket valve lifters. Camshaft journal bearing surfaces and all camshaft rubbing surfaces except lobe tips were coated. The direct acting bucket shims were etched with a cross hatch pattern to a depth sufficient to sustain a SFL film coating on the shim rubbing surfaces subjected to high surface loads. The SFL coated valvetrain torque was evaluated and compared with uncoated baseline torque. Coating the cam bearing journal surfaces alone with II-25D SFL reduced valvetrain friction losses 8 to 17% for 250 to 2000 rpm cam speed range (i.e. 500 - 4000 rpm engine speed). When bucket tappet and shims were also coated with the SFL, further significant reductions in coated valvetrain friction were observed.

Diesel engines, especially CR (Common Rail) DI (Direct Injection) TCI (Turbo Charged Inter-cooled), share a wide acceptance in the passenger car market due to the enormous torque and flexibility at low engine speed. A pre - condition for the use of a diesel engine in a motorcycle is that the disadvantages like combustion noise and visible smoke are reduced or eliminated. Moreover the fuel economy and performance characteristics of a diesel engine are dedicated to be used in a touring or large displacement motorcycle. The AVL engine concept is the first high performance diesel engine to be specially designed for motorcycles in terms of packaging and styling. To compensate for the limited engine speed range a gearbox with a wide ratio spread is required. This leads to a manual transmission with at least 6 gears or an automatic transmission. For the AVL concept an AMT (Automated Manual Transmission) was selected.

Abstract The ASTM D130 was first issued in 1922 as a tentative standard for the detection of corrosive sulfur in gasoline. A clean copper strip was immersed in a sample of gasoline for three hours at 50°C with any corrosion or discoloration taken to indicate the presence of corrosive sulfur. Since that time, the method has undergone many revisions and has been applied to many petroleum products. Today, the ASTM D130 standard is the leading method used to determine the corrosiveness of various fuels, lubricants, and other hydrocarbon-based solutions to copper. The end-of-test strips are ranked using the ASTM Copper Strip Corrosion Standard Adjunct, a colored reproduction of copper strips characteristic of various degrees of sulfur-induced tarnish and corrosion, first introduced in 1954. This pragmatic approach to assessing potential corrosion concerns with copper hardware has served various industries well for a century.

Two Cummins B5.9L engines were fueled with 100% biodiesel in excess of 48 months by the Agricultural Engineering Department at the University of Missouri-Columbia. The engines used to power Dodge pickups. The engine lubricating oil was sampled at 1000 mile intervals for analysis. Statistical analysis of the engine lubricating oil indicated that the wear metal levels in the lubricating oil were normal. A reduction in power was noted when the engines were tested using a chassis dynamometer. The 1991 pickup has been driven 110,451 km and the 1992 pickup has been driven approximately 177,022 km. The pickups averaged 6.9 km/L. Engine fuel efficiency and material compatibility issues are addressed in the paper.

Nine identical 40-ft. transit buses were operated on B20 and diesel for a period of two years - five of the buses operated exclusively on B20 (20% biodiesel blend) and the other four on petroleum diesel. The buses were model year 2000 Orion V equipped with Cummins ISM engines, and all operated on the same bus route. Each bus accumulated about 100,000 miles over the course of the study. B20 buses were compared to the petroleum diesel buses in terms of fuel economy, vehicle maintenance cost, road calls, and emissions. There was no difference between the on-road average fuel economy of the two groups (4.41 mpg) based on the in-use data, however laboratory testing revealed a nearly 2% reduction in fuel economy for the B20 vehicles. Engine and fuel system related maintenance costs were nearly identical for the two groups until the final month of the study.

Because of the size and weight of the various components going into the machine, new approaches were used to solve the practical limitations of manufacturing facilities, shipping clearances, and erection procedures. Although the general appearance of the machine is similar to previous units, there are a number of new design features incorporated in the unit. This paper will be limited to the major design considerations as follows: adaption to stripping two seams of coal simultaneously; dipper with two doors; computerized hydraulic steering maintaining Ackerman correction; double end drive crawlers and belt tensioning; and electrical innovations.

The phenomenal success of the small car is leading to many engineering changes in the automobile industry. It has brought increased emphasis on weight reduction on both small and full-size cars. Improving reliability and designing to eliminate grease fittings have also become important objectives.

General Motors Powertrain Division has developed the next generation big block V8 engine for introduction in the 1996 model year. In addition to meeting tighter emission and on-board diagnostic legislation, this engine evolved to meet both customer requirements and competitive challenges. Starting with the proven dependability of the time tested big block V8, goals were set to substantially increase the power, torque, fuel economy and overall pleaseability of GM's large load capacity gasoline engine. The need for this new engine to meet packaging requirements in many vehicle platforms, both truck and OEM, as well as a requirement for minimal additional heat rejection over the engine being replaced, placed additional constraints on the design.

General Motors Powertrain Group (GMPTG) has developed an all new small block V8 engine, designated LS1, for introduction into the 1997 Corvette. This engine was designed to meet both customer requirements and competitive challenges while also meeting the ever increasing legislated requirements of emissions and fuel economy. This 5.7L V8 provides increased power and torque while delivering higher fuel economy. In addition, improvements in both QRD and NVH characteristics were made while meeting packaging constraints and achieving significant mass reductions.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

The paper presents a 1D-3D numerical model to simulate the scavenging and combustion processes in a small-size spark-ignition two-stroke engine. The engine is crankcase scavenged and can be operated with both gasoline and Natural Gas (NG). The analysis is performed with a modified version of the KIVA3V code, coupled to an in-house developed 1D model. A time-step based, two-way coupled procedure is fully described and validated against a reference test. Then, a 1D-3D simulation of the whole two-stroke engine is carried out in different operating conditions, for both gasoline and NG fuelling. Results are compared with experimental data including instantaneous pressure signals in the crankcase, in the cylinder and in the exhaust pipe. The procedure allows to characterize the scavenging process and quantify the fresh mixture short-circuiting, as well as to analyze the development of the NG combustion process for a diluted mixture, typically occurring in a two-stroke engine.

In order to extend the CAI operation range in 4-stroke mode and maximize the benefit of low fuel consumption and emissions in CAI mode, 2-stroke CAI combustion is revived operating in a GDI engine with poppet valves, where the conventional crankcase scavenging is replaced by boosted scavenging. The CAI combustion is achieved through the inherence of the 2-Stroke operation, which is retaining residual gas. A set of flexible hydraulic valve train was installed on the engine to vary the residual gas fraction under the boosting condition. The effects of spark timing, intake pressure and short-circuiting on 2-stroke CAI combustion and its emissions are investigated and discussed in this paper. Results show the engine could be controlled to achieve CAI operation over a wide range of engine speed and load in the 2-stroke mode because of the flexibility of the electro-hydraulic valvetrain system.

In this work, the authors assess the potential of the 2-stroke concept applied to Range Extender engines, proposing 3 different configurations: 1) Supercharged, Compression Ignition; 2) Turbocharged, Compression Ignition; 3) Supercharged, Gasoline Direct Injection. All the engines feature a single power cylinder of 0.49l, external air feed by piston pump and an innovative induction system. The scavenging is of the Loop type, without poppet valves, and with a 4-stroke like lubrication system (no crankcase pump). Engine design has been supported by CFD simulations, both 1D (engine cycle analysis) and 3D (scavenging, injection and combustion calculations). All the numerical models used in the study are calibrated against experiments, carried out on engines as similar as possible to the proposed ones.