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Modern natural gas-to-liquids (GTL) conversion processes (Fischer-Tropsch liquid fuels (FTL)) offers an attractive means for making synthetic liquid fuels. Military diesel and jet fuels are procured under Commercial Item Description (CID) A-A-52557 (based on ASTM D 975) and MIL-DTL-83133/MIL-DTL-5624 (JP-8/JP-5), respectively. The Single Fuel Forward (single fuel in the battlefield) policy requires the use of JP-8 or JP-5 (JP-8/5). Fuel properties crucial to fuel system/engine performance/operation are identified for both old and new tactical/non-tactical vehicles. The 21st Century Truck program is developing technology for improved safety, reduced harmful exhaust emissions, improved fuel efficiency, and reduced cost of ownership of future military and civilian ground vehicles (in the heavy duty category having gross vehicle weights exceeding 8500 pounds).[1]

A set of experiments was performed to investigate the effects of relative air-fuel ratio, inlet boost pressure, and compression ratio on engine knock behavior. Selected operating conditions were also examined with simulated hydrogen rich fuel reformate added to the gasoline-air intake mixture. For each operating condition knock limited spark advance was found for a range of octane numbers (ON) for two fuel types: primary reference fuels (PRFs), and toluene reference fuels (TRFs). A smaller set of experiments was also performed with unleaded test gasolines. A combustion phasing parameter based on the timing of 50% mass fraction burned, termed “combustion retard”, was used as it correlates well to engine performance. The combustion retard required to just avoid knock increases with relative air-fuel ratio for PRFs and decreases with air-fuel ratio for TRFs.

For gasoline engine, thermal efficiency can be improved by using lean burn. However, combustion instability occurs when gasoline engine is operated on lean condition. Hydrogen has features that can be used for improving combustion stability of gasoline engine. In this paper, an experimental study of hydrogen effect on lean limit was carried out using a four-cylinder 2.0L turbo gasoline direct injection engine. The engine torque was fixed at 110Nm on 1600RPM, 2000RPM and 2400RPM. The results showed that lean limit was extended and brake thermal efficiency was improved by hydrogen addition. Especially, at lower engine speed, the large improvement of lean limit was achieved. However, improvement of brake thermal efficiency was achieved at high speed. HC and CO2 emissions were decreased and NO emissions increased with hydrogen addition. CO emissions were slightly reduced with hydrogen addition.

An experimental study was performed to investigate the effects of various intake charge motion control valves (CMCVs) on mixture preparation, combustion, and hydrocarbon (HC) emissions during the cold start-up process of a port fuel injected spark ignition (SI) engine. Different charge motions were produced by three differently shaped plates in the CMCV device, each of which blocked off 75% of the engine's intake ports. Time-resolved HC, CO and CO2 concentrations were measured at the exhaust port exit in order to achieve cycle-by-cycle engine-out HC mass and in-cylinder air/fuel ratio. Combustion characteristics were examined through a thermodynamic burn rate analysis. Cold-fluid steady state experiments were carried out with the CMCV open and closed. Enhanced charge motion with the CMCV closed was found to shorten the combustion duration, which caused the location of 50% mass fraction burned (MFB) to occur up to 5° CA earlier for the same spark timing.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

The oxidation of soot (carbon black) which is assisted by Pt/CeO2 catalyst is studied using a flow reactor system simulating the condition of diesel exhaust. In this study, the temperature programmed oxidation (TPO) scheme is mainly used for different NO and O2 concentrations and soot oxidation rate is evaluated by monitoring both CO and CO2 concentrations. Pt/CeO2 catalyst lowers the temperature of the peak CO/CO2 concentrations significantly when there is either NO or O2. Oxidation starts at 200°C and the peak CO2 concentration is observed at 360°C, which depends on the amount of catalyst and NO concentration. The effect of catalyst on NO2 recycling is also investigated. For this purpose, two different types of sample have been prepared. For the mixed case, 10mg of carbon black is mixed with 50mg of Pt/CeO2 catalyst under conditions of loose contact. For the unmixed case, the catalyst layer is placed on top of soot layer without mixing.

Two features to facilitate chemical reactions at low temperature, non-thermal plasma and the weak dependency of photocatalyst on temperature, have been exploited by many researchers to effectively decompose hydrocarbon emissions emitted until the light-off of a three-way catalyst in spark ignition engines. To develop a realizable emissions reduction reactor, as part of such effort, this study investigates for the three model gases, propylene, n-butane and acetylene: 1) the conversion efficiency of the emissions reduction reactor, which utilizes the effect of dissociation, ionization-by-collision of the non-thermal plasma and the photocatalytic effect of TiO2, and 2) the concentrations of the products such as acetaldehyde, acetic acid, polymerized hydrocarbons and NO2. The operating parameters to obtain the plasma energy density ranging from 7.8 to 908 J/L were varied.

Experiments were performed to identify the knock trends of lean hydrocarbon-air mixtures, and such mixtures enhanced with hydrogen (H2) and carbon monoxide (CO). These enhanced mixtures simulated 15% and 30% of the engine's gasoline being reformed in a plasmatron fuel reformer [1]. Knock trends were determined by measuring the octane number (ON) of the primary reference fuel (mixture of isooctane and n-heptane) supplied to the engine that just produced audible knock. Experimental results show that leaner operation does not decrease the knock tendency of an engine under conditions where a fixed output torque is maintained; rather it slightly increases the octane requirement. The knock tendency does decrease with lean operation when the intake pressure is held constant, but engine torque is then reduced.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.

Measurements were made of exhaust histories of the following species: unburned hydrocarbons (HC), carbon monoxide, carbon dioxide, oxygen, and nitric oxide (NO). The measurements show that the exhaust flow can be divided into two distinct phases: a leading gas low in HC and high in NO followed by a trailing gas high in HC and low in NO. Calculations of time resolved equivalence ratio throughout the exhaust process show no evidence of a stratified combustion. The exhaust mass flow rate is time resolved by forcing the flow to be locally quasi-steady at an orifice placed in the exhaust pipe. The results with the quasi-steady assumption are shown to be consistent with the measurements. Predictions are made of time resolved mass flow rate which compare favorably to the experimental data base. The composition and flow histories provide sufficient information to calculate the time resolved flow rates of the individual species measured.