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Hydrogen produced from regenerative sources has the potential to be a sustainable substitute for fossil fuels. A hydrogen internal combustion engine has good combustion characteristics, such as higher flame propagation velocity, shorter quenching distance, and higher thermal conductivity compared with hydrocarbon fuel. However, storing hydrogen is problematic since the energy density is low. Hydrogen can be chemically stored as a hydrocarbon fuel. In particular, an organic hydride can easily generate hydrogen through use of a catalyst. Additionally, it has an advantage in hydrogen transportation due to its liquid form at room temperature and pressure. We examined the application of an organic hydride in a spark ignition (SI) engine. We used methylcyclohexane (MCH) as an organic hydride from which hydrogen and toluene (TOL) can be reformed. First, the theoretical thermal efficiency was examined when hydrogen and TOL were supplied to an SI engine.

This study investigates the mechanisms of solubility, ignition, combustion and emission of ethanol diesel blend fuel for the prospect of using ethanol diesel blend in a Premixed Compression Ignition (PCI) engine. Ethanol diesel blend fuel of ethanol blend ratio 20vol% (E20) does not solubilize in atmospheric temperature, though will solubilize when heated to 323K. When applying ethanol diesel blend fuel to a PCI engine, combustion characteristics changes, which increases ignition delay and decreases the rate-of-pressure-rise. We speculated that the above combustion characteristics were shown as a result of the following three reasons: a leaner mixture caused by increase in ignition delay, fuel adhesion to cavity wall by ethanol and diesel fuels evaporation characteristics, and a decrease in combustion rate by adding ethanol.

Homogeneous charge compression ignition (HCCI) combustion of methane was performed using dimethyl ether (DME) as an ignition improver. The ignition mechanisms of the methane/DME/air HCCI process were investigated on the basis of the chemical kinetics. The engine test was also conducted to verify the calculation results, and to determine the operation range. Analysis of the results showed that DME was an excellent ignition improver for methane, having two functions of temperature rise and OH radical supply. It was also shown that the operation range was extended to an overall equivalence ratio of 0.54 without knocking, by controlling DME quantity.

Dimethyl ether (DME) holds promise as an alternative to diesel fuel. However, its physical properties are not similar to those of conventional diesel fuel. The P-V, bulk modulus and viscosity of DME are derived as a function of temperature and pressure. As a result, the Weber and Reynolds number of DME is very large as compared with that of diesel fuel. So, the spray characteristics of DME are not those of a liquid spray but similar to those of gas spray. The spray formation is strongly affected by the fuel flow in the nozzle. The Computational Fluid Dynamics (CFD) and experiments are examined to analyze the fuel flow in the nozzle. The DME physical properties make some difference to the flow in the nozzle, in comparison with those of diesel. As a CFD result, cavitation in the injection nozzle is more frequent with DME than with diesel oil. From experimental results, the temperature in the nozzle sac is higher with DME than with diesel oil.

To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength.

Dimethyl ether(DME) is a promising new alternative fuel not only diesel fuel but also power generation, fuel cell and city gas. However, the physical properties are not similar to those of conventional diesel fuel. The P-v, bulk modulus and viscosity of DME are derived as a function of temperature and pressure. As a Result, the Weber and Reynolds number of DME is very large as compared with that of diesel fuel. So, the spray characteristics of DME is not the liquid spray but similar to that of gas spray. The spray formation is strongly affected by the fuel flow in the nozzle. The Computational Fluid Dynamics (CFD) and the experiments are examined to analyze the fuel flow in the nozzle. The DME physical properties make some difference of the flow in the nozzle, comparing with those of diesel. As a CFD result, cavitation in the injection nozzle is more frequent with DME than with diesel oil.

Characteristics of dimethyl ether spray formation were observed using schlieren photography, and the combustion characteristics and performance of a dimethyl ether-operated diesel engine were investigated. Accordingly, this paper describes the basic characteristics of engine performance and the potential for decreased exhaust emissions, as well as discussing problems concerning the practical application of dimethyl ether-operated diesel engines.

Computational analysis on the mechanism and control method for DME fueled HCCI type combustion was carried out on the basis of the chemical kinetics. The calculation results were verified experimentally using a single cylinder test engine. Analysis of the results showed that DME oxidation is governed by production/consumption behavior of OH, because DME oxidation is initiated by dehydrogenation with OH radicals. It was also shown that the overall oxidation reaction could be controlled by adding substances which react competitively with OH in the dehydrogenation reactions of DME. Of the substances we tested, formaldehyde was most effective. It was confirmed by engine testing that by adding a small amount of formaldehyde to the DME/air mixture, the heat evolved in the low temperature reactions was reduced and the reaction appearance timing was retarded.

To better understand the combustion characteristics of DME, emission intensities of DME combustion radicals from a pre-mixed burner flame were measured by a spectroscope and photomultiplier, Results were compared to other fuels, such as methane and butane. Large peaks in the band spectra from pre-mixed and diffusion DME flames were found near 310 nm, 430 nm, and 515 nm, arising from OH, CH and C2, respectively. The DME emission intensities decreased with increasing the equivalence ratio in this study. Notably, the relative decrease in the C2 band spectra peak was greater than that of the OH band. Comparing the pre-mixed DME and butane flames, the butane band spectra peaks were similar in shape, but much stronger than those for DME. However, it was remarkable that CH and C2 band spectra peaks decreased only slightly with increase in equivalence ratio compared to the DME case.

Recently, dimethyl ether (DME) has been attracting much attention as a clean alternative fuel, since the thermal efficiency of DME powered diesel engine is comparable to diesel fuel operation and soot free combustion can be achieved. In this experiment, the effect of ambient pressure on DME spray was investigated with observation of droplet size such as Sauter mean diameter (SMD) by the shadowgraph and image processing method. The higher ambient pressure obstructs the growth of DME spray, therefore faster breakup was occurred, and liquid column was thicker with increasing the ambient pressure. Then engine performances and exhaust emissions characteristics of DME diesel engine were investigated with various compression ratios. The minimum compression ratio for the easy start and stable operation was obtained at compression ratio of about 12.

Dimethyl Ether (DME) is one of the major candidates for the next generation fuel for compression ignition (CI) engines. It has good self-ignitability and would not produce particulate, even at rich conditions. DME has proved to be able to apply to ordinary diesel engines with minimal modifications, but its combustion characteristics are not completely understood. In this study, the behavior of a DME spray and combustion process of a direct injection CI engine fueled with DME was investigated by combustion observation and in-cylinder gas sampling. To distinguish evaporated and non-evaporated zones of a spray, direct and schlieren imaging were carried out. The sampled gas from a DME spray was analyzed by gas chromatography, and the major intermediate product histories during ignition period were analyzed.

Based on the knowledge that cavitation in a nozzle enhances the atomization of fuel spray, fuel modification is conducted by blending Dimethyl Ether (DME). Because the boiling point of DME is -24.8°C, it may easily take place during the cavitation in an injection nozzle. Furthermore, there is a soot reduction effect caused by the oxygenated fuels. The oxygen content in the DME is 34.8%, which accelerates soot reduction in the combustion chamber. The experimental results are compared with those of DiMethoxyMethan (Methylal: DMM), a blend of gas-oil. The ignition temperatures of DME and DMM are 235°C and 236°C, the boiling temperatures of DME and DMM are -24.8°C and 42.1°C, and the oxygen contents of DME and DMM are 34.8% and 42.1%, respectively. In addition to the oxygenated fuel, a propane blend of gas-oil was also used as a blended fuel in order to examine the effects of the boiling point and oxygen content of the fuel.

In this study, a homogeneous mixture of natural-gas and air was used in a compression ignition engine to reduce NOx emissions and improve thermal efficiency. In order to control ignition timing and combustion, a small amount of DME was mixed with the natural-gas. Engine performance and the exhaust characteristics were investigated experimentally. Results show the following: the engine can run over quite a large load range if a certain amount of DME is added into natural-gas. By optimizing the proportion of DME to natural-gas, NOx emissions can be lowered to near zero levels if the mixture is lean enough. Thermal efficiency is higher than that obtained with normal diesel fuel operation.

In this study, the NO emission characteristics of a dimethyl ether fueled compression ignition (CI) engine were studied, and a suitable combustion control concept was developed. A three-zone thermo-chemical model was used to understand the basic NO formation characteristics with dimethyl ether. The experimental study was carried out using a small direct-injection diesel engine. Comparison of the experimental and calculated results showed that the dimethyl ether / air mixing process was relatively slow compared with diesel fuel, which is the main reason for the relatively high NO emissions with dimethyl ether operation, in spite of its lower adiabatic flame temperature. To reduce the high temperature period, turbulence was introduced into the combustion chamber by a high-turbulence combustion system, which reduced NO emissions. It became clear that acceleration of the mixing process is an important factor for NO reduction with dimethyl ether spray combustion.

Dimethyl Ether (DME) is a promising new alternative fuel for compression ignition DI engines. However, some problems arise from the poor lubricity of DME. Breakdown of the film bearing between needle and sleeve of the injector can lead to mechanical wear and leakage, a problem that is not mitigated easily. For example, the application of returning the leakage to fuel tank could raise a back pressure on the injection needle. This pressure can affect injection rate and consequently engine performance. In this study, fuels based on various DME to gas oil (diesel fuel) ratios were investigated, in part. Physical and chemical properties of DME and gas oil are shown to lead to mutual solubility at any ratio. Blended fuels have a higher lubricity compared with pure’ DME and a better injection spray compared with pure gas oil.

A direct fuel-injection two-stroke cycle engine operated with neat methanol was investigated. The engine performance, combustion and exhaust-gas characteristics were analyzed experimentally and compared for operation with a carburetor, EFI injection at the intake manifold, and EFI injection at the scavenging port. The power and the brake thermal efficiency of the direct fuel-injection engine were higher than those of engines operated with a carburetor and either of the two EFI methods. The exhausted unburnt fuel of the direct fuel-injection engine was lower than that for operation with a carburetor, and formaldehyde and the CO concentration were of the same level as for operation with the carburetor and EFI methods. The NOx concentration of the direct fuel-injection was half the level of the result of carburetor operation.

The engine performance, combustion characteristics and exhaust emission of pre-chamber type compression ignition engine operated by various biomass fuels were investigated experimentally. The biomass fuel investigated in this report are an emulsified fuel made with gas oil and hydrous ethanol or hydrous methanol, an emulsified fuel made with hydrous methanol and rape-seed oil, and neat rape-seed oil, and gas oil. There are small deviations of the experimental results between the biomass fuels, however, the general tendencies of the engine performances and exhaust gas characteristics operated by biomass fuels are as follows: The brake thermal efficiency during biomass fuel operation becomes maximum at a certain injection timing as well as those of the gas oil operation. And this injection timing is advanced with increasing the biomass content in the fuel.

Reduction of soot and NOx emissions from a prechamber-type diesel engine is studied by employing both chemical and physical aspects of the fuel and induction method. Fuel modification was performed to produce several forms of composite fuel: solution of alcohol and gas oil (JIS No. 1); emulsification and mixture of methyl alcohol-gas oil prepared by off- and in-line fuel systems; and separate injection of fuels into the pre- and main-chamber.

In this study, accordingly, methanol fuel was supplied in suction pipe with carburetor and with electronically-controlled fuel injector (EFI), which located in front of the suction valve, to clear experimentally the influence of various factors, such as the methanol-gasoline ratio (M/F), the difference in fuel feed system, the number of times of injection [ni], the injection timing (θinj), the engine speed (N), the volumetric efficiency (η v), the suction pipe wall temperature (tw), the water content in fuel (yw) etc., on the engine performance (the output and the thermal efficiency), the exhaust characteristics (NOx, CO, UBF and HCHO concentrations) and combustion variation as well as obtaining a guideline to establish the optimum condition. The authors will be report about the results of above-mentioned.