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Stringent regulations on fuel economy have driven major innovative changes in the internal combustion engine design. (E.g. CAFE fuel economy standards of 54.5 mpg by 2025 in the U.S) Vehicle manufacturers have implemented engine infrastructure changes such as downsizing, direct injection, higher compression ratios and turbo-charging/super-charging to achieve higher engine efficiencies. Fuel properties therefore, have to align with these engine changes in order to fully exploit the possible benefits. Fuel octane number is a key metric that enables high fuel efficiency in an engine. Greater resistance to auto-ignition (knock) of the fuel/air mixture allows engines to be operated at a higher compression ratio for a given quantity of intake charge without severely retarding the spark timing resulting in a greater torque per mass of fuel burnt. This attribute makes a high octane fuel a favorable hydrocarbon choice for modern high efficiency engines that aim for higher fuel economy.

Many vehicle and engine test studies have shown that the fuel efficiency of automobiles can be improved by reducing friction between moving parts. Typically, organic friction modifiers such as glycerol monooleate (GMO) or metal containing friction modifiers such as molybdenum dithiocarbamate (MoDTC) have been added to engine oils to reduce boundary friction and improve fuel efficiency. These traditional friction modifiers act by forming either a self-assembled organic film (in the case of GMO) or a Mo-disulfide chemical film (in the case of MoDTC). More recently, the ability of inorganic tungsten disulfide (WS2) nanoparticles to reduce boundary friction has been described. Martin has proposed that WS2 nanoparticles are transported into a contact zone where they are compressed and peel open like an onion to form a film. In this study, oil-soluble inorganic nanoparticles containing cerium (Ce) and zinc (Zn) have been synthesized.

This paper explores the possibility of on-board fuel classification for fuel property adaptive compression-ignition engine control system. The fuel classifier is designed to on-board classify the fuel that a diesel engine is running, including alternative and renewable fuels such as bio-diesel. Based on this classification, the key fuel properties are provided to the engine control system for optimal control of in-cylinder combustion and exhaust treatment system management with respect to the fuel. The fuel classifier employs engine input-output response characteristics measured from standard engine sensors to classify the fuel. For proof-of-concept purposes, engine input-output responses were measured for three different fuels at three different engine operating conditions. Two neural-network-based fuel classifiers were developed for different classification scenarios. Of the three engine operating conditions tested, two conditions were selected for the fuel classifier to be active.

A 2003 heavy-duty diesel engine (2002 emissions level) was used to test a representative biodiesel fuel as well as the methyl esters of several different fatty acids. The fuel variables included degree of saturation, the oxygen content, and carbon chain length. In addition, two pure normal paraffins with the corresponding chain lengths of two of the methyl esters were also tested to determine the impact of chain length. The dependent variables were the NOx and the particulate emissions (PM). The results indicated that the primary fuel variable affecting the emissions is the oxygen content. The emissions results showed that the highest oxygen content test fuel had the lowest emissions of both NOx and PM. As compared to the baseline diesel fuel the NOx emissions were reduced by 5 percent and the PM emissions were reduced by 83 percent.

Southwest Research Institute (SwRI) is exploring the feasibility of extending the performance and fuel efficiency of the spark ignition (SI) engine to match that of the emission constrained compression (CI) engine, whilst retaining the cost effective 3-way stoichiometric aftertreatment systems associated with traditional SI light duty engines. The engine concept, which has a relatively high compression ratio and uses heavy EGR, is called “HEDGE”, i.e. High Efficiency Durable Gasoline Engine. Whereas previous SwRI papers have been medium and heavy duty development focused, this paper uses results from simulations, with some test bed correlations, to predict multicylinder torque curves, brake thermal efficiency and NOx emissions as well as knock limit for light and medium duty applications.

SwRI has developed a new technology concept involving the use of high EGR rates coupled with a high-energy ignition system in a gasoline engine to improve fuel economy and emissions. Based on a single-cylinder study [1], this study extends the concept of a high compression ratio gasoline engine with EGR rates > 30% and a high-energy ignition system to a multi-cylinder engine. A 2000 MY Isuzu Duramax 6.6 L 8-cylinder engine was converted to run on gasoline with a diesel pilot ignition system. The engine was run at two compression ratios, 17.5:1 and 12.5:1 and with two different EGR systems - a low-pressure loop and a high pressure loop. A high cetane number (CN) diesel fuel (CN=76) was used as the ignition source and two different octane number (ON) gasolines were investigated - a pump grade 91 ON ((R+M)/2) and a 103 ON ((R+M)/2) racing fuel.

A technology path has been identified for development of a high efficiency, durable, gasoline engine, targeted at achieving performance and emissions levels necessary to meet heavy-duty, on-road standards of the foreseeable future. Initial experimental and numerical results for the proposed technology concept are presented. This work summarizes internal research efforts conducted at Southwest Research Institute. An alternative combustion system has been numerically and experimentally examined. The engine utilizes gasoline as the fuel, with a combination of enabling technologies to provide high efficiency operation at ultra-low emissions levels. The concept is based upon very highly-dilute combustion of gasoline at high compression ratio and boost levels. Results from the experimental program have demonstrated engine-out NOx emissions of 0.06 g/hp/hr, at single-cylinder brake thermal efficiencies (BTE) above thirty-four percent.

Researchers at Southwest Research Institute (SwRI) have been working for the past several years on the fundamental and practical aspects of homogeneous charge compression ignition (HCCI) operation of reciprocating engines. Much of the work has focused on the use of diesel fuel. The work at SwRI has, however, demonstrated that there are fundamental limitations on the use of current diesel fuels in HCCI engines. The results of engine and constant volume combustion bomb experiments are presented and discussed. The engine experiments were used to identify important fuel properties that must be included in a fuel specification for HCCI fuels. The primary properties relate to the distillation characteristics and the ignition characteristics. The engine test provided preliminary guidance on the distillation requirements and an indication of the important ignition requirements.

Additive control of DIG injector coking was investigated on two dynamometer-operated engines and validated in a vehicle. The first engine was a Nissan research “mule” engine designed to severely coke the injectors so that additive effect could be more easily discriminated. Initial additive screening and optimization was carried out in this engine and a few chosen candidates of the Mannich chemistry-type were further optimized in the second engine, and in a vehicle. The second engine, which was also dynamometer operated, was an advanced wall-guided design capable of both homogeneous and stratified operation. On this engine we were able to optimize the Mannich additive “Man C-2” separately in two different carrier systems to show a carrier effect, and by manipulating the purity of the base detergent Man C-2 to show a detergent activity modulation by trace co-products.

The engine-out emissions and fuel consumption rates for a modern, heavy-duty diesel engine were compared when fueling with a conventional diesel fuel and three water-blend-fuel emulsions. Four different fuels were studied: (1) a conventional diesel fuel, (2) PuriNOx,™ a water-fuel emulsion using the same conventional diesel fuel, but having 20% water by mass, and (3,4) two other formulations of the PuriNOx™ fuel that contained proprietary chemical additives intended to improve combustion efficiency and emissions characteristics. The emissions data were acquired with three different injection-timing strategies using the AVL 8-Mode steady-state test method in a Caterpillar 3176 engine, which had a calibration that met the 1998 nitrogen oxides (NOX) emissions standard.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

This paper reports on the fourth part of a continued study on further research and development with the automated Ignition Quality Tester (IQT™). Research over the past six years (reported in SAE papers #961182, 971636 and 1999-01-3591) has demonstrated the capabilities of this automated apparatus to measure the ignition quality and accurately determine a derived cetane number (DCN) for a wide range of middle distillate and non-conventional diesel fuels. The present paper reports on a number of separate investigations supporting these continued studies.

This paper presents the findings of some fundamental characterisation of the deposits that form on the injectors of an air-assisted DISI automotive engine, including the effect of these deposits on engine performance when operated in different combustion modes, with varying fuel composition and additive content. A root cause analysis was undertaken, including an assessment of injector temperature and deposit chemistry. Fuels from a matrix designed around the European year 2000 gasoline specifications for T90, olefin and aromatic levels were used to study the effect of fuel composition on deposit formation. Two commercial gasoline detergent additives, of different chemistries, were used to investigate the impact on deposit formation. The results of the fuels study and deposit analysis are consistent with published theories concerning fuel composition impact on combustion chamber deposit (CCD).

A new combustion concept has been developed and tested for improving the low to moderate load efficiency and NOx emissions of natural gas engines. This concept involves operation of a dual-fuel natural gas engine on Homogeneous Charge Compression Ignition (HCCI) in the load regime of idle up to 35 % of the peak torque. A dual-fuel approach is used to control the combustion phasing of the engine during HCCI operation, and conventional spark-ignited natural gas combustion is used for the high-load regime. This concept has resulted in an engine with power output and high-load fuel efficiency that are unchanged from the base engine, but with a 10 - 15 % improvement to the low to moderate load fuel efficiency. In addition, the engine-out NOx emissions during HCCI operation are over 90% lower than on spark-ignited natural gas operation over the equivalent load range.

The U.S. Environmental Protection Agency (EPA) formed a Heavy-Duty Engine Working Group (HDEWG) in the Mobile Sources Technical Advisory Subcommittee in 1995. The goal of the HDEWG was to help define the role of the fuel in meeting the future emissions standards in advanced technology engines (beyond 2004 regulated emissions levels). A three-phase program was developed. This paper presents the results of the statistical analysis of the data collected in the Phase II program. Included is a description of the design of the fuel test matrix, and a listing of the regression equations developed to predict emissions as a function of fuel density, cetane number, monoaromatics, and polyaromatics. Also included is a description of selected analyses of the emissions from a smaller set of fuel data that allowed direct comparison of the effects of natural and boosted cetane number.

In 1995, US Environmental Protection Agency (EPA) formed the Heavy-Duty Engine Working Group (HDEWG). The objective of the group was to assess the role diesel fuel could play in meeting exhaust emission standards proposed for model year 2004+ heavy-duty diesel engines. The group developed a three-phase program to achieve this objective. This paper describes the development of test fuels used in Phase 2 of the EPA HDEWG Program to investigate the effect of fuel properties on heavy-duty diesel engine emissions. It discusses the design of the fuel matrix, reviews the process of test fuel preparation and presents the results of a multi-laboratory fuel analysis program. Fuel properties selected for investigation included density, cetane number, mono- and polyaromatic hydrocarbon content.

In 1997 the US EPA formed a Heavy-Duty Engine Working Group (HDEWG) in the Mobile Sources Technical Advisory Subcommittee to address the questions related to fuel property effects on heavy-duty diesel engine emissions. The Working Group consisted of members from EPA and the oil refining and engine manufacturing industries. The goal of the Working Group was to help define the role of the fuel in meeting the future emissions standards in advanced technology engines (beyond 2004 regulated emissions levels). To meet this objective a three-phase program was developed. Phase I was designed to demonstrate that a prototype engine, located at Southwest Research Institute, represented similar emissions characteristics to that of certain manufacturers prototype engines. Phase II was designed to document the effects of selected fuel properties using a statistically designed fuel matrix in which cetane number, density, and aromatic content and type were the independent variables.

We report on a comprehensive fuel additive study where two different detergent chemistry types, Mannichs and polyetheramines, are ranked with regard to injector deposit control in a research direct-injected gasoline (DIG) engine. The engine used was a conventional dual-sparkplug, 2.2-liter Nissan engine modified for direct injection using one of the sparkplug holes. The engine was run under 20% rich conditions to accelerate injector deposit formation. The two detergent chemistry types are shown to perform quite differently with the Mannichs showing superior performance. The Mannich detergent chemistries can reduce the DIG injector flow loss after using Howell EEE fuel from a high of 11.23% to a low of 3.14% whereas the best polyetheramine detergent chemistry tested reduced it to 8.17%. One of the Mannichs was further tested in a year 2000 specification gasoline with 150 ppm sulfur, and a North American type gasoline with 420 ppm sulfur.

The time of, and location where ignition first occurs in a diesel fuel spray were investigated in a rapid compression machine (RCM) using the two–dimensional techniques of silicone oil particle scattering imaging (SSI), and the planar laser induced fluorescence (LIF) of formaldehyde. Formaldehyde has been hypothesized to be one of the stable intermediate species marking the start of oxidation reactions in a transient spray under compression ignition conditions. In this study, the LIF images of the formaldehyde formed in a diesel fuel spray during ignition process have been successfully obtained for the first time by exciting formaldehyde with the 3rd harmonic of the Nd:YAG laser. SSI images of the vaporizing spray, and the LIF images of formaldehyde were obtained together with the corresponding time record of combustion chamber pressures at initial ambient temperatures ranging from 580 K to 790 K.

The specific goal of this project was to determine if there is a difference in the lube oil degradation rates in a heavy-duty diesel engine equipped with an EGR system, as compared to the same configuration of the engine, but minus the EGR system. A secondary goal was to develop FTIR analysis of used lube oil as a sensitive technique for rapid evaluation of the degradation properties of lubricants. The test engine selected for this work was a Caterpillar 3176 engine. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to meet the 2004 emissions standards. The most significant changes in the lubricant occurred during the first 50-100 hours of operation. The results clearly demonstrated that the use of EGR has a significant impact on the degradation of the engine lubricant.