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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Technologies for improving the fuel economy of gasoline engines have been vigorously developed in recent years for the purpose of reducing CO2 emissions. Increasing the compression ratio for improving thermal efficiency and downsizing the engine based on fuel-efficient operating conditions are good examples of technologies for enhancing gasoline engine fuel economy. A direct-injection system is adopted for most of these engines. Direct injection can prevent knocking by lowering the in-cylinder temperature through fuel evaporation in the cylinder. Therefore, direct injection is highly compatible with downsized engines that frequently operate under severe supercharging conditions for improving fuel economy as well as with high compression ratio engines for which susceptibility to knocking is a disadvantage.

Technologies for improving the fuel economy of gasoline engines have been vigorously developed in recent years for the purpose of reducing CO2 emissions. Increasing the compression ratio is an example of a technology for improving the thermal efficiency of gasoline engines. A significant issue of a high compression ratio engine for improving fuel economy and low-end torque is prevention of knocking under a low engine speed. Knocking is caused by autoignition of the air-fuel mixture in the cylinder and seems to be largely affected by heat transfer from the intake port and combustion chamber walls. In this study, the influence of heat transfer from the walls of each part was analyzed by the following three approaches using computational fluid dynamics (CFD) and experiments conducted with a multi-cooling engine system. First, the temperature rise of the air-fuel mixture by heat transfer from each part was analyzed.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

The aim of this study is to gain a better understanding of the mechanism of knocking with respect to flame propagation behavior based on 3D simulations conducted with the Universal Coherent Flamelet Model. Flame propagation behavior under the influence of in-cylinder flow was analyzed on the basis of the calculated results and experimental visualizations. Tumble and swirl flows were produced in the cylinder by inserting various baffle plates in the middle of the intake port. A comparison of the measured and calculated flame propagation behavior showed good agreement for various in-cylinder flow conditions. The results indicate that in-cylinder flow conditions vary the flame propagation shape from the initial combustion period and strongly influence the occurrence of knocking.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

In 2006, Nissan began limited leasing of the X-TRAIL FCV equipped with their in-house developed Fuel Cell (FC) stack. Since then, the FC stack has been improved in cost, size, durability and cold start-up capability with the aim of promoting full-scale commercialization of FCVs. However, reduction of cost and size has remained a significant challenge because limited mass transport through the membrane electrode assembly (MEA) has made it difficult to increase the rated current density of the FC. Furthermore, it has been difficult to reduce the variety of FC stack components due to the complex stack configuration. In this study, improvements have been achieved mainly by adopting an advanced MEA to overcome these difficulties. First, the adoption of a new MEA and separators has improved mass transport through the MEA for increased rated current density. Second, an integrated molded frame (IMF) has been adopted as the MEA support.

It is generally known that NOx reacts with unburned gasoline, olefins in particular, to form sludge precursors. In this study, the authors investigated the process by which NOx and unburned gasoline mix into the engine oil and analyzed the mechanism whereby stop and go driving accelerates sludge formation. It has been found that NOx detected in the engine oil as nitrite ions mixes into the oil in the crankcase. The NOx concentration in the engine oil increases rapidly when the crankcase gas temperature is nearly equal to the dew point of the water vapor in the crankcase. Unburned gasoline is mainly absorbed into the oil through the oil film on the cylinder walls and the oil in the ring grooves. During low-temperature engine operation in stop-go driving (i.e., when the vehicle is stopped), NOx and unburned gasoline are absorbed into the engine oil and, in high-temperature engine operation (i.e., when the vehicle is moving), NOx and unburned gasoline are released from the oil.

Reducing friction in the crankshaft main bearings is an effective means of improving the fuel efficiency of reciprocating internal combustion engines. To realize these improvements, it is necessary to understand the lubricating conditions, in particular the oil film pressure distributions between crankshaft and bearings. In this study, we developed a thin-film pressure sensor and applied it to the measurement of engine main bearing oil film pressure in a 4-cylinder, 2.5 L gasoline engine. This thin-film sensor is applied directly to the bearing surface by sputtering, allowing for measurement of oil film pressure without changing the shape and rigidity of the bearing. Moreover, the sensor material and shape were optimized to minimize influence from strain and temperature on the oil film pressure measurement. Measurements were performed at the No. 2 and 5 main bearings.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

To improve the fuel economy via high EGR, combustion stability is enhanced through the addition of hydrogen, with its high flame-speed in air-fuel mixture. So, in order to realize on-board hydrogen production we developed a fuel reformer which produces hydrogen rich gas. One of the main issues of the reformer engine is the effects of reformate gas components on combustion performance. To clarify the effect of reformate gas contents on combustion stability, chemical kinetic simulations and single-cylinder engine test, in which hydrogen, CO, methane and simulated gas were added to intake air, were executed. And it is confirmed that hydrogen additive rate is dominant on high EGR combustion. The other issue to realize the fuel reformer was the catalyst deterioration. Catalyst reforming and exposure test were carried out to understand the influence of actual exhaust gas on the catalyst performance.

Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.

A dynamometer-mounted four-cylinder Saturn engine was used to accumulate combustion chamber deposits (CCD), using an additized fuel. During each deposit accumulation test, the HC emissions were continuously measured. The deposit thickness at the center of the piston was measured at the beginning of each day. After the 50 and 35-hour tests, HC emissions were measured with isooctane, benzene, toluene, and xylene, with the deposited engine, and again after the deposits had been cleaned from the engine. The HC emissions showed a rapid rise in the first 10 to 15 hours and stabilization after about 25 hours of deposit accumulation. The HC increase due to CCD accumulation accounted for 10 to 20% of the total engine-out HC emissions from the deposit build-up fuel and 10 to 30% from benzene, isooctane, toluene, and xylene, making CCDs a significant HC emissions source from this engine. The HC emissions stabilized long before the deposit thickness.

Achieving a multi-cylinder engine with excellent noise/vibration character sties and low friction at the main bearings requires an optimal design not only for the crankshaft construction but also for the bearing support system of the cylinder block. To accomplish that, it is necessary to understand crankshaft system behavior and the bearing load distribution for each of the main bearings. Crankshaft system behavior has traditionally been evaluated experimentally because of the difficulty in performing calculations to predict resonance behavior over the entire engine speed range. A coupled crankshaft-block analysis method has been developed to calculate crankshaft system behavior by treating vibration and lubrication in a systematic manner. This method has the feature that the coupled behavior of the crankshaft and the cylinder block is analyzed by means of main bearing lubrication calculations. This paper presents the results obtained with this method.

A multiple-link variable compression ratio (VCR) mechanism is suitable for a long-stroke engine by providing the following characteristics: (1) a nearly symmetric piston stroke and (2) an upper link that stays vertical around the time of the maximum combustion pressure. These two characteristics work to reduce force inputs to the piston. The maximum inertial force around top dead center is reduced by the effect of the first characteristic. The second characteristic is effective in reducing piston side thrust force and helps ease piston pin lubrication. Because of the combined effect of these characteristics, the piston skirt can be made smaller and the piston pin can be shortened. That makes it possible for the piston skirt and piston pin to move between the counterweights, resulting in a downward extension of the piston stroke. As a result, a longer-stroke engine mechanism can be achieved without making the cylinder block taller.

The purpose of this study is to clarify the state of heat loss to the cylinder liner of the tested engine of which piston and cylinder head were previously measured. The authors' group developed an original measurement technique of instantaneous surface temperature at the cylinder liner wall using thin-film thermocouples. The temperature was measured at 36 points in total. The instantaneous heat flux was calculated by heat transfer analysis using measurement results of the temperature at the wall. As a result, the heat loss ratio to all combustion chamber walls is evaluated except the intake and exhaust valves.

The SR engine is a new medium-size, all aluminum (cylinder block, head, rocker cover and oil pan) in-line 4-cylinder gasoline powerplant developed as a replacement for CA engine in Nissan's compact passenger cars. The development aim set for this engine was to achieve excellent power output and ample torque in the middle-and high-speed ranges, as well as a clear, linear engine sound up to the red zone. These performance targets have been achieved through the use of the 4-valve-per-cylinder DOHC design featuring a Y-shaped valve rocker arm system. This system allows a straight intake port for high power output and a narrow valve angle for a compact combustion chamber. The result is ample torque output as well as good fuel economy.