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A numerical investigation on a series of Diesel spray experiments in constant-volume vessels is proposed. Non reacting conditions were used to assess the spray models and to determine the grid size required to correctly predict the fuel-air mixture formation process. To this end, not only computed liquid and vapor penetrations were compared with experimental data, but also a detailed comparison between computed and experimental mixture fraction distributions was performed at different distances from the injector. Grid dependency was reduced by introducing an Adaptive Local Mesh Refinement technique (ALMR) with an arbitrary level of refinement. Once the capabilities of the current implemented spray models have been assessed, reacting conditions at different ambient densities and temperatures were considered. A Perfectly Stirred Reactor (PSR) combustion model, based on a direct integration of complex chemistry mechanisms over a homogenous cell, was adopted.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Using alternative fuels like Natural Gas (NG) has shown good potentials on heavy duty engines. Heavy duty NG engines can be operated either lean or stoichiometric diluted with EGR. Extending Dilution limit has been identified as a beneficial strategy for increasing efficiency and decreasing emissions. However dilution limit is limited in these types of engines because of the lower burnings rate of NG. One way to extend the dilution limit of a NG engine is to run the engine on Hythane (natural gas + some percentage hydrogen). Previously effects of Hythane with 10% hydrogen by volume in a stoichiometric heavy duty NG engine were studied and no significant changes in terms of efficiency and emissions were observed. This paper presents results from measurements made on a heavy duty 6-cylinder NG engine. The engine is operated with NG and Hythane with 25% hydrogen by volume and the effects of these fuels on the engine performance are studied.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

Pursuing a sustainable energy scenario for transportation requires the blending of renewable oxygenated fuels such as alcohols into commercial hydrocarbon fuels. From a chemical kinetic perspective, this requires the accurate description of both hydrocarbon reference fuels (n-heptane, iso-octane, toluene, etc.) and oxygenated fuels chemistry. A recent systematic investigation of linear C2-C5 alcohols ignition in a rapid compression machine at p = 10-30 bar and T = 650- 900 K has extended the scarcity of fundamental data at such conditions, allowing for a revision of the low temperature chemistry for alcohol fuels in the POLIMI mechanism. Heavier alcohols such as n-butanol and n-pentanol present ignition characteristic of interest for application in HCCI engines, due to the presence of the hydroxyl moiety reducing their low temperature reactivity compared to the parent linear alkanes (i.e. higher octane number).

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

In the last years automotive industry has shown a growing interest in exploring the field of vehicle dynamic control, improving handling performances and safety of the vehicle, and actuating devices able to optimize the driving torque distribution to the wheels. These techniques are defined as torque vectoring. The potentiality of these systems relies on the strong coupling between longitudinal and lateral vehicle dynamics established by tires and powertrain. Due to this fact the detailed (and correct) simulation of the dynamic behaviour of the driveline has a strong importance in the development of these control systems, which aim is to optimize the contact forces distribution. The aim of this work is to build an integrated vehicle and powertrain model in order to provide a proper instrument to be used in the development of such systems, able to reproduce the dynamic interaction between vehicle and driveline and its effects on the handling performances.

Due to the increasing pressure to develop small-size and low-cost after-treatment systems meeting the legislative demands it is desirable to integrate multiple functionalities and exploit any possible synergies. Typical examples include DPFs catalyzed with deNOx catalysts, as well as LNT-SCR combinations using layered coating technology. The present paper deals with the modeling challenges involved for the proper simulation of such advanced concepts. Key role in such advanced simulation attempts has the coupling between diffusion-reaction phenomena, which is captured through intra-layer modeling. All investigations in this paper deal with the application of possible combined LNT-SCR system configurations. The simulation results show that a dual bed LNT- passive SCR configuration offers substantial NOx emissions reductions compared to a single LNT catalyst and effectively controls secondary NH3 emissions produced during LNT regeneration phases.

Achieving upcoming HD emissions legislation, Euro VI/EPA 10, is a challenge for all engine manufacturers. A likely solution to meet the NOx limit is to use a combination of EGR and SCR. Combining these two technologies poses new challenges and possibilities when it comes to optimization and calibration. Using a complete system approach, i.e., considering the engine and the aftertreatment system as a single unit, is important in order to achieve good performance. Optimizing the complete system is a tedious task; first there are a large number of variables which affect both emissions and fuel consumption (injection timing, EGR rate, urea dosing, injection pressure, pilot/post injections, for example). Secondly, the chemical reactions in the SCR catalyst are substantially slower than the dynamics of the diesel engine and the rest of the system, making the optimization problem time dependent.

The current research focuses in understanding how inlet pressure, EGR, combustion phasing, engine speed and pilot main ratio are affecting the main parameters of the combustion (e.g. efficiency, NOx, soot, maximum pressure rise rate) in the novel concept of injecting high octane number fuels in partially premixed combustion. The influence of the above mentioned parameters was studied by performing detailed sweeps at 32 bar fuel MEP (c.a. 16-18 bar gross IMEP); three different kinds of gasoline were tested (RON: 99, 89 and 69). The experiments were ran in a single cylinder heavy duty engine; Scania D12. At the end of these sweeps the optimized settings were computed in order to understand how to achieve high efficiency, low emissions and acceptable maximum pressure rise rate.

The Co-ordinating European Council (CEC) for the development of performance tests for transportation fuels, lubricants and other fluids has set up a working group to develop a laboratory pump rig test able to discriminate between diesel fuels of different lubricity performance. This test was expected to correlate with the performance of fuels and Fuel Injection Equipment (FIE) in the field, therefore providing a way to avoid costly field trials. This test could also enhance the understanding of the results from the High Frequency Reciprocating Rig (HFRR) method. The CEC working group was supported by representatives of Oil Companies, Test Houses, Additive Companies and all the European FIE Manufacturers. After a thorough investigative phase, the group focused on a Bosch VE 4 distributor-type pump run according to the Bosch WP2 test cycle. This choice was also widely accepted throughout the industry.

The rare occurrence during city driving of the exhaust temperature levels required for ceramic trap regeneration without catalytic aid, seems to be the main reason of delay in wide application of the trap. The use of catalysts seems to be more or less necessary. Study of the catalytic activity during trap regeneration had not been very effective so far. This holds equally true for the case of catalyzed trap as for the case of catalytic fuel additives. The lack of a satisfactory theory for the explanation and prediction of catalytic activity, directed international research and development towards the quest of the optimum catalyst, which could support a very simple and low-cost regeneration system. The new approach to the explanation of catalytic activity presented in this paper, denies the above assumption.

Many new combustion concepts are currently being investigated to further improve engines in terms of both efficiency and emissions. Examples include homogeneous charge compression ignition (HCCI), lean stratified premixed combustion, stratified charge compression ignition (SCCI), and high levels of exhaust gas recirculation (EGR) in diesel engines, known as low temperature combustion (LTC). All of these combustion concepts have in common that the temperatures are lower than in traditional spark ignition or diesel engines. To further improve and develop combustion concepts for clean and highly efficient engines, it is necessary to develop new computational tools that can be used to describe and optimize processes in nonstandard conditions, such as low temperature combustion.

Partially Premixed Combustion (PPC) is a combustion concept by which it is possible to get low smoke and NOx emissions simultaneously. PPC requires high EGR levels to extend the ignition delay so that air and fuel mix prior to combustion to a larger extent than with conventional diesel combustion. This paper investigates the operating region of single injection PPC for three different fuels; Diesel, low octane gasoline with similar characteristics as diesel and higher octane standard gasoline. Limits in emissions are defined and the highest load that fulfills these requirements is determined. The investigation shows the benefits of using high octane number fuel for Multi-Cylinder PPC. With high octane fuel the ignition delay is made longer and the operating region of single injection PPC can be extended significantly. Experiments are carried out on a multi-cylinder heavy-duty engine at low, medium and high speed.

Stoichiometric operation of Spark Ignited (SI) Heavy Duty Natural Gas (HDNG) engines with a three way catalyst results in very low emissions however they suffer from bad gas-exchange efficiency due to use of throttle which results in high throttling losses. Variable Geometry Turbine (VGT) is a good practice to reduce throttling losses in a certain operating region of the engine. VTG technology is extensively used in diesel engines; it is very much ignored in gasoline engines however it is possible and advantageous to be used on HDNG engine due to their relatively low exhaust gas temperature. Exhaust gas temperatures in HDNG engines are low enough (lower than 760 degree Celsius) and tolerable for VGT material. Traditionally HDNG are equipped with a turbocharger with waste-gate but it is easy and simple to replace the by-pass turbocharger with a well-matched VGT.

Partially Premixed Combustion is a concept able to combine low smoke and NOx emissions with high combustion controllability and efficiency. It is of interest to be able to utilize PPC in a large operating region in order to meet the Euro VI emission legislation without relying on NOx aftertreatment. This paper investigates the differences in PPC characteristics for three fuels; Diesel Swedish Mk 1, Low Octane Gasoline (70 Octane) and US Standard Gasoline (87 Octane). Engine operating conditions, combustion characteristics, emissions and efficiency are in focus. The experiments were carried out at a range of operating points on a Volvo MD13 which is a six-cylinder heavy-duty engine. At each operating point three combinations of EGR level and λ-value were evaluated. 1. High EGR/High λ, 2. High EGR/Reduced λ, and 3. Reduced EGR/High λ.

Combination of flow field measurements, shown in this paper, give new information on the effect of engine run parameters to formation of different flow fields inside piston bowl. The measurements were carried out with particle image velocimetry (PIV) technique in optical engine. Good set of results was achieved even though the feasibility of this technique in diesel engines is sometimes questioned. Main challenge in diesel engines is background radiation from soot particles which is strong enough to conceal the PIV signal. Window staining in diesel engine is also a problem, since very high particle image quality is needed for velocity analysis. All measurements were made in an optical heavy-duty diesel engine. Optical design of engine was Bowditch type [1]. The engine was charged and equipped with exhaust gas recirculation (EGR). The exhaust gas level was monitored by oxygen concentration and the level was matched to former soot concentration measurements.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.