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The combustion and exhaust emission characteristics of a DME fueled HCCI engine were investigated. Different fuel injection strategies were tested under various injection quantities and timings with exhaust gas recirculation (EGR). The combustion phase in HCCI was changed by an in-cylinder direct injection and EGR, due to changes in the in-cylinder temperature and mixture homogeneity. The gross indicated mean effective pressure (IMEPgross) increased and the hydrocarbon (HC) and carbon monoxide (CO) emissions decreased as the equivalence ratio was augmented. The IMEPgross with direct injection was greater than with the port injection due to retarded ignition timing resulting from latent heat of direct injected DME fuel. It was because that most of burn duration was completed before top dead center owing to higher ignitability for DME with high cetane number. However, HC and CO emissions were similar for both injection locations.

Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.

Dimethyl-ether combustion with pilot injection was investigated in a single cylinder direct injection diesel engine equipped with a common-rail injection system. Combustion characteristics and emissions were tested with dimethyl-ether and compared with diesel fuel. The main injection timing was fixed to have the best timings for maximum power output. The total injected fuel mass corresponded to a low heating value of 405 joules per cycle at 800 rpm. The fuel quantity and the injection timing of the pilot injection were varied from 8 to 20% of the total injected mass and from 50 to 10 crank angle degrees before the main injection timing, respectively. Ignition delay decreased with pilot injection. The effects of pilot injection were less significant with DME combustion than with diesel. Pilot injection caused the main combustion to increase in intensity resulting in decreased emissions of hydrocarbons, carbon monoxide and particulate matter.

The combustion, knock characteristics and exhaust emissions in an engine were investigated under homogeneous charge compression ignition operation fueled with liquefied petroleum gas with regard to variable valve timing and the addition of di-methyl ether. Liquefied petroleum gas was injected at an intake port as the main fuel in a liquid phase using a liquefied injection system, while a small amount of di-methyl ether was also injected directly into the cylinder during the intake stroke as an ignition promoter. Different intake valve timings and fuel injection amount were tested in order to identify their effects on exhaust emissions, combustion and knock characteristics. The optimal intake valve open timing for the maximum indicated mean effective pressure was retarded as the λTOTAL was decreased. The start of combustion was affected by the intake valve open timing and the mixture strength (λTOTAL) due to the volumetric efficiency and latent heat of vaporization.

A comprehensive methodology for predicting the transient thermal response of spark-ignition engines subject to time-varying boundary conditions is presented. The approach is based on coupling a cycle-resolved quasi-dimensional simulation of in-cylinder thermodynamic events with a resistor-capacitor (R-C) thermal network of the various component and fluid interactions throughout the engine and exhaust system. The dynamic time step of the thermal solution is limited by either the frequency of the prescribed time-dependent boundary conditions or by the minimum thermal time constant of the R-C network. To demonstrate the need for fully-coupled, transient thermodynamic and heat transfer solutions, model behavior is first explored for step-change and staircase variations of engine operating conditions.

A detailed chemical model was implemented in the KIVA-3V two dimensional CFD code to investigate the effects of the spray cone angle and injection timing on the PCCI combustion process and emissions in an optical research diesel engine. A detailed chemical model for Primary Reference Fuel (PRF) consisting of 157 species and 1552 reactions was used to simulate diesel fuel chemistry. The model validation shows good agreement between the predicted and measured pressure and emissions data in the selected cases with various spray angles and injection timings. If the injection is retarded to -50° ATDC, the spray impingement at the edge of the piston corner with 100° injection angle was shown to enhance the mixing of air and fuel. The minimum fuel loss and more widely distributed fuel vapor contribute to improving combustion efficiency and lowering uHC and CO emissions in the engine idle condition.

Low temperature diesel combustion with a large amount of exhaust gas recirculation in a direct injection diesel engine was investigated. Tests were carried out under various engine speeds, injection pressures, injection timings, and injection quantities. Exhaust emissions and brake specific fuel consumption were measured at different torque and engine speed conditions. High rates of exhaust gas recirculation led to the simultaneous reduction of nitrogen oxide and soot emissions due to a lower combustion temperature than conventional diesel combustion. However, hydrocarbon and carbon monoxide emissions increased as the combustion temperature decreased because of incomplete combustion and the lack of an oxidation reaction. To overcome the operating range limits of low temperature diesel combustion, increased intake pressure with a modified turbocharger was employed.

Two-stage injection strategy was studied in dimethyl-ether homogeneous charge compression ignition engine combustion. An early direct injection, main injection, was applied to form a premixed charge followed by the second injection after the start of heat release. Experiments were carried out in a single-cylinder direct-injection diesel engine equipped with a common-rail injection system, and the combustion performance and exhaust emissions were tested with the various second injection timings and quantities. Engine speed was 1200 rpm, and the load was fixed at 0.2 MPa IMEP. Main injection timing for homogeneous mixture was fixed at −80 CAD, and the fuel quantity was adjusted to the fixed load. Second injection quantity was varied from 1 to 5 mg, and the timing was selected according to the heat release rate of the HCCI combustion without second injection.

A numerical study has been conducted to investigate possible extension of the low load limit of the HCCI operating range by charge stratification using direct injection. A wide range of SOI timings at a low load HCCI engine operating condition were numerically examined to investigate the effect of DI. A multidimensional CFD code KIVA3v with a turbulent combustion model based on a modified flamelet approach was used for the numerical study. The CFD code was validated against experimental data by comparing pressure traces at different SOI’s. A parametric study on the effect of SOI on combustion has been carried out using the validated code. Two parameters, the combustion efficiency and CO emissions, were chosen to examine the effect of SOI on combustion, which showed good agreement between numerical results and experiments. Analysis of the in-cylinder flow field was carried out to identify the source of CO emissions at various SOI’s.

The effect of the composition of propane (C₃H₈) and butane (C₄H₁₀) in liquefied petroleum gas (LPG) was investigated in a dual-fuel HCCI engine fueled with di-methyl ether (DME) and LPG. The composition of LPG affects DME-LPG dual fuel HCCI combustion due to the difference in the physical properties of propane that and butane such as octane number, auto-ignition temperature and heat of vaporization. DME was injected directly into the cylinder at various injection timing from 160 to 350 crank angle degrees (CAD). LPG was injected at the intake port with a fixed injection timing at 20 CAD. It was found that power output was increased with propane ratio. This gain in power output resulted from increased expansion work due to the better anti-knock properties of propane. However, higher propane ratio made combustion efficiency decrease because of the suppression in low temperature reaction of DME which determines heat release amount of high temperature reaction.

A diesel-fueled premixed charged compression ignition (PCCI) combustion technique using a two-stage injection strategy has been investigated in a single cylinder optical engine equipped with a common-rail fuel system. Although PCCI combustion has the advantages of reducing NOx and PM emissions, difficulties in vaporization of a diesel fuel and control of the combustion phase hinder the development of the PCCI engine. A two-stage injection strategy was applied to relieve these problems. The first injection, named as main injection, was an early direct injection of diesel fuel into the cylinder to achieve premixing with air. The second injection was a diesel injection of a small quantity (1.5 mm3) as an ignition promoter and combustion phase controller near TDC. Effects of injection pressure, injected fuel quantity and compression ratio were studied with variation of an intake air temperature.

A PC-based, computationally-efficient, quasi-dimensional simulation of HCCI engine performance and emissions has been developed with the intent to bridge the gap between zero-dimensional and sequential fluid-mechanic - thermo-kinetic models. The model couples a detailed chemistry description, a core gas model, a predictive boundary layer model, and a ring-dynamics crevice flow model. The thermal boundary layer, which is axially discretized to account for the relative piston motion, is modeled using compressible energy arguments. The ring-pack crevice zone is modeled using a coupled ring dynamic and flow model. The physically-based mathematical model is solved within the context of a single simulation framework, which lends to flexibility and expediency in performing a range of parametric studies. The simulation was validated under turbo-charged conditions using data obtained from a Caterpillar 3500 test engine.

Premixed compression ignition (PCI) combustion was implemented using advanced injection strategy and exhaust gas recirculation in a direct-injection single-cylinder diesel engine. The injection timing swept experiment using a baseline injector, which had an injection angle of 146° and 8 nozzle holes, obtained three types of combustion regime: conventional diesel combustion for an injection timing of 10° CA (crank angle) BTDC (before top dead center), PCI combustion for an injection timing of 40° CA BTDC and homogeneous charge compression ignition (HCCI) combustion for an injection timing of 80° CA BTDC. PCI combustion can be verified by burn duration analysis. The burn duration, which was defined as the period from 10% to 90% of the accumulated heat release, was very short in PCI combustion but not in the others. PCI combustion with an injection timing of 40° CA BTDC was achieved in a range of an exhaust gas recirculation (EGR) rate from 0% to around 40%.

The effect of pilot injection and exhaust gas recirculation (EGR) on premixed charge compression ignition (PCCI) combustion was investigated in a single-cylinder direct-injection diesel engine with low engine speed and low load. The injection timing of PCCI combustion was fixed at 25 ~ 30 crank angle degree before top dead center (°CA BTDC) based on the ignition delay and power output. The level of oxides of nitrogen (NOx) emissions of PCCI combustion was 68% lower than that of conventional diesel combustion owing to the reduction of near-stoichiometric region which is well known as the main source of NOx formation. However, the indicated mean effective pressure (IMEP), hydrocarbon (HC), particulate matter (PM) and carbon monoxide (CO) emissions deteriorated compared with conventional diesel combustion because of early injection, advanced combustion phase and lowered combustion temperature. EGR has been applied to PCCI combustion.

The influence of fuel injection pressure and intake pressure on conventional and low temperature diesel combustion was investigated in a light duty diesel engine. The in-cylinder pressure and exhaust emissions were measured and analyzed in each operating condition. The two combustion regimes were classified in terms of intake oxygen concentrations, which were adjusted by varying the amount of exhaust gas recirculation. The fuel injection quantity and injection timing were fixed in order to minimize the influencing factors. Fuel injection pressures of 40 MPa and 120 MPa were used to verify the effect of the fuel injection pressure in both combustion regimes. The injection pressure significantly affected the combustion phase in the low temperature diesel combustion regime due to the longer premixing time relative to the conventional diesel combustion regime.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Engine-out CO emission and fuel conversion efficiency were measured in a highly-dilute, low-temperature diesel combustion regime over a swirl ratio range of 1.44-7.12 and a wide range of injection timing. At fixed injection timing, an optimal swirl ratio for minimum CO emission and fuel consumption was found. At fixed swirl ratio, CO emission and fuel consumption generally decreased as injection timing was advanced. Moreover, a sudden decrease in CO emission was observed at early injection timings. Multi-dimensional numerical simulations, pressure-based measurements of ignition delay and apparent heat release, estimates of peak flame temperature, imaging of natural combustion luminosity and spray/wall interactions, and Laser Doppler Velocimeter (LDV) measurements of in-cylinder turbulence levels are employed to clarify the sources of the observed behavior.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Five small two-stroke engine designs were tested at different air/fuel ratios, under steady state and transient cycles. The effects of combustion chamber design, carburetor design, lean burning, and fuel composition on performance, hydrocarbon and carbon monoxide emissions were studied. All tested engines had been designed to run richer than stoichiometric in order to obtain satisfactory cooling and higher power. While hydrocarbon and carbon monoxide emissions could be greatly reduced with lean burning, engine durability would be worsened. However, it was shown that the use of a catalytic converter with acceptably lean combustion was an effective method of reducing emissions. Replacing carburetion with in-cylinder fuel injection in one of the engines resulted in a significant reduction of hydrocarbon and carbon monoxide emissions.