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Selected ferritic stainless steel sheets for exhaust applications were tested under thermo-mechanical fatigue (TMF) condition in the temperature range of 400-800 °C with partial constraint. Straight welded tubes were used as the testing coupons to withstand large compression without buckling, and to understand the effect of welding as well. Repeated tests confirmed the observed failure scenario for each material type. The hysteresis loop behaviors were also simulated using the mechanism-based integrated creep and fatigue theory (ICFT) model. Although more development work is needed, for quick material screening purpose this type of testing could be a very cost effective solution for materials and tube weld development for exhaust applications.

Strain controlled thermo-mechanical fatigue (TMF) tests were conducted on a high Silicon ductile cast iron (SiMo) as the baseline material and a similar SiMo cast iron with aluminum addition (SiMoAl). The much improved fatigue life with aluminum addition is analyzed using the integrated creep-fatigue theory (ICFT) in combination with the metallurgical analysis on the tested coupons. Addition of about 3 wt.% Aluminum significantly improved TMF life of the SiMo cast iron. The results are explained by elimination of brittleness at middle temperature range, the higher flow stress, lower creep rate and higher oxidation resistance from Al addition.

One of the major sources of chlorine in automobiles is polyvinyl chloride (PVC). When old discarded automobiles enter the recycling loop by far the largest percent of this material finds its way into the solid waste fraction known as automobile shredder residue (ASR). While the majority of this waste is currently disposed of in landfills new processes are currently being evaluated to recycle and recover the valuable resources contained in this solid waste. Pyrolysis, the thermal cracking of the polymeric materials present in ASR, to recover the petrochemical hydrocarbons is one such technology which is receiving attention. However, like combustion with energy recovery, the pyrolysis process is receiving close scrutiny in terms of its environmental impact. These concerns have centered around the fate of the chlorine and the heavy metals present in the ASR.

The development of an optimized heat treatment schedule, with the aim of maximizing strength and relieving tensile residual stress, is important to prevent in-service cylinder distortion in Al alloy engine blocks containing cast-in gray iron liners. However, to effectively optimize the engine block heat treatment schedule, the current solutionizing parameters must be analyzed and compared to the as-cast condition to establish a baseline for residual stress relief. In this study, neutron diffraction was carried out to measure the residual stress along the aluminum cylinder bridge following solution heat treatment. The stresses were measured in the hoop, radial and axial orientations and compared to a previous measured as-cast (TSR) engine block. The results suggest that solution heat treatment using the current production parameters partially relieved tensile residual stress in the Al cylinder bridge, with stress relief being more effective near the bottom of the cylinder.

The continued need of vehicle weight reduction provides impetus for research into the development of novel automotive casting alloys and their processing technologies. Where possible, ferrous components are being replaced by aluminum (Al) and magnesium (Mg) alloy counterparts. This transition, however, requires a systematic optimization of the alloys and their manufacturing processes to enable production of defect-free castings. In this context, prevention of hot tears remains a challenge for Al and Mg alloy thin-wall castings. Hot tears form in semi-solid alloy subjected to localized tensile stress. Classical methods of stress measurement present numerous experimental limitations. In this research, neutron diffraction (ND) was used as a novel tool to obtain stress maps of castings and to quantify the effect of two processes used to eliminate hot tears in permanent mold castings: 1) increasing of the mold temperature during casting of Mg alloys, and 2) grain refinement of Al alloys.

A study was conducted to assess the performance and castability of a new AA6061 aluminum alloy variant specially designed for semi-solid pressure die casting. The AA6061 alloy has very desirable mechanical properties for the fabrication of automotive parts. However, it has limited castability due to its low silicon content. It is not well suited for shape casting processes which are, for their part, very interesting in terms of production costs for complex-shaped automotive components. In an effort to meet automotive industry requirements, new AA6061 alloy variants have been developed by Rio Tinto Alcan researchers over the past years, aiming to improve the castability of the alloy while maintaining its desirable mechanical properties, by increasing its die-filling capacity, decreasing its hot tearing tendency. The study described herein is an example of how the performance of a single variant was assessed in terms of castability. The full study was conducted on six separate variants.

Development of lightweight alloys suitable for automobile applications has been of great importance to the automotive industry in recent years. The use of 319 type aluminum alloy in the production of gasoline engine blocks is an example of this shift towards light alloys for large automobile components. However, excessive residual stress along the cylinder bores of these engine blocks may cause problems during engine operation. Therefore, in this study, neutron diffraction was used to evaluate residual stresses along the aluminum cylinder bridge and the gray cast iron liners. The strains were measured in the hoop, radial, and axial orientations, while stresses were subsequently calculated using generalized Hooke's law. The results suggest that the residual stress magnitude for the aluminum cylinder bridge was tensile for all three measured components and gradually increased with cylinder depth towards the bottom of the cylinder.

Cast aluminum-silicon alloys have witnessed a notable increase in use in the automotive and transport industry. The ability of these alloys to be easily cast into complex shapes coupled with a favorable strength-to-weight ratio has given them an edge over cast irons. One particular area of casting which has received further and further attention is the area of semi-solid casting, where an alloy casting is prepared as slurry with flow properties that resemble both solid and liquid. In the present work, the effects of iron additions on the mechanical properties of a 319 semi-solid alloy were studied. This alloy was prepared using the SEED process, as developed by Rio Tinto Alcan in collaboration with the Aluminum Technology Centre of NRC Canada. The SEED (Swirled Enthalpy Equilibration Device) process is a novel rheocasting method which yields a semi-solid slurry from the mechanical stirring and cooling of the molten aluminum.

The influence of fuel aromatics type on the particulate matter (PM) and NOx exhaust emissions of a heavy-duty, single-cylinder, DI diesel engine was investigated. Eight fuels were blended from conventional and oil sands crude oil sources to form five fuel pairs with similar densities but with different poly-aromatic (1.6 to 14.6%) or total aromatic (14.3 to 39.0%) levels. The engine was tuned to meet the U.S. EPA 1994 emission standards. An eight-mode, steady-state simulation of the U.S. EPA heavy-duty transient test procedure was followed. The experimental results show that there were no statistically significant differences in the PM and NOx emissions of the five fuel pairs after removing the fuel sulphur content effect on PM emissions. However, there was a definite trend towards higher NOx emissions as the fuel density, poly-aromatic and total aromatic levels of the test fuels increased.

Homogeneous Charge Compression Ignition (HCCI) combustion characteristics of dual-stage autoignition fuels were examined over the speed range of 600 to 1700 rpm using a Cooperative Fuels Research (CFR) engine. A fuel vaporizer was used to preheat and partially vaporize the fuel inside the intake plenum. The air and fuel were well-mixed prior to entering the cylinder. Since low temperature heat release (LTHR) is known to be an important factor that affects HCCI combustion of fuels that exhibit dual-stage autoignition behavior, a detailed heat release analyses were performed on both time and crank angle bases. At the lower and upper speeds, the operating ranges were compared as a function of air/fuel ratio (AFR) and exhaust gas recirculation (EGR) from the knocking to misfiring limits. The AFR-EGR operating region was more limited at 1700 rpm than at 900 rpm for the commercial ULSD fuel. Combustion stability was problematic at higher engine speeds.

Lightweight tubular products offering enhanced stiffness and strength have always been of major concern for transportation and recreational applications. Hence, industries have turned to complex-shaped tubes to increase product performance and reduce energy costs. High-performance aluminum alloys, like 7075 for instance, have good mechanical properties such as high strength, but low formability at ambient temperature. Fortunately, hot tensile tests on 7075 samples have yielded an increase in formability with temperature. Therefore, testing has recently been launched at the Aluminum Technology Center to develop a new product application. More precisely, a 1,000-ton hydraulic press was equipped with +600°C heating plates and fitted with a bicycle handlebar mold. The plates provide 10 separate heating zones that can be adjusted independently. A thermo-mechanical model was also developed using LS-DYNA to determine tube temperatures around the heating zones.

Structural adhesive joints are expected to retain integrity in their entire service-life that normally involves cyclic loading concurrent with environmental exposure. Under such a severe working condition, effective determination of fatigue life at different temperatures is crucial for reliable joint design. The main goal of this work was thus defined as evaluation of fatigue performance of adhesive joints at their extreme working temperatures in order to be compared with their fracture properties under static loading. A series of standard double-cantilever-beam (DCB) specimens have been bonded by three structural 3M epoxy adhesives selected from different applications. The specimens were tested under monotonic and cyclic opening loads (mode-I) in order to evaluate the quasi-static and fatigue performances of selected adhesives at room temperature, 80°C and -40°C.

Strain-controlled low-cycle fatigue (LCF) experiments were conducted on ductile cast iron at total strain rates of 1.2/min, 0.12/min and 0.012/min in a temperature range of RT ~ 800°C. An integrated creep-fatigue (ICF) life prediction framework is proposed, which embodies a deformation mechanism based constitutive model and a thermomechanical damage model. The constitutive model is based on the decomposition of inelastic deformation into plasticity and creep mechanisms, which can describe both rate-independent and rate-dependent cyclic responses under wide strain rate and temperature conditions. The damage model takes into consideration of i) plasticity-induced fatigue, ii) intergranular embrittlement, iii) creep and iv) oxidation. Each damage form is formulated based on the respective physical mechanism/strain.

Computational fluid dynamics (CFD) model has been widely applied in internal combustion (IC) engine research. The integration of chemical kinetic model with CFD provides an opportunity for researchers to investigate the detailed chemical reactions for better understanding the combustion process of IC engines. However, the simulation using CFD has generally focused on the examination of primary parameters, such as temperature and species distributions. The detailed investigation on chemical reactions is limited. This paper presents the development of a post-processing tool capable of calculating the rate of production (ROP) of interested species with the known temperature, pressure, and concentration of each species in each cell simulated using CONVERGE-SAGE CFD model.

The exhaust emissions from a single-cylinder version of a heavy-duty diesel engine with exhaust gas recirculation (EGR) were studied using 12 diesel fuels derived from oil sands and conventional sources. The test fuels were blended from 22 refinery streams to produce four fuels (two from each source) at three different total aromatic levels (10, 20, and 30% by mass). The cetane numbers were held constant at 43. Exhaust emissions were measured using the AVL eight-mode steady-state test procedure. PM emissions were accurately modeled by a single regression equation with two predictors, total aromatics and sulphur content. Sulphate emissions were found to be independent of the type of sulphur compound in the fuel. NOx emissions were accurately modeled by a single regression equation with total aromatics and density as predictor variables. PM and NOx emissions were significantly significantly affected by fuel properties, but crude oil source did not play a role.

In this study, the AVL 8-mode steady-state simulations of the EPA transient test were conducted on a two litre single cylinder Ricardo Proteus research engine using two fuel matrices, one consisting fuels having different cetane numbers and the other consisting fuels of different aromatic contents. Engine exhaust emissions of NOx, HC, CO, CO2 and particulates were measured at two different injection timings. The results show that the single cylinder engine behaves similarly as a number of multi-cylinder production engines. The 8-mode simulation was also shown to produce exhaust emissions close to those obtained from the EPA transient test procedure. The cetane number response of the research engine indicates that an increase in cetane number of the fuel with cetane improvers reduced NOx emissions but increased particulate emissions.

The effects of cetane number, aromatics content and 90% distillation temperature (T90) on HCCI combustion were investigated using a fuel matrix designed by the Fuels for Advanced Combustion Engines (FACE) Working Group of the Coordinating Research Council (CRC). The experiments were conducted in a single-cylinder, variable compression ratio, Cooperative Fuel Research (CFR) engine. The fuels were atomized and partially vaporized in the intake manifold. The engine was operated at a relative air/fuel ratio of 1.2, 60% exhaust gas recirculation (EGR) and 900 rpm. The compression ratio was varied over the range of 9:1 to 15:1 to optimize the combustion phasing for each fuel, keeping other operating parameters constant. The results show that cetane number and T90 distillation temperature significantly affected the combustion phasing. Cetane number was clearly found to have the strongest effect.

The effects of cetane number and the cetane enhancing additives on diesel exhaust emissions were investigated on a single cylinder DI research engine. The engine used in this study incorporates the features of contemporary medium-to-heavy duty diesel engines and is tuned to US EPA 1994 emission standards. The engine experiments were run using the AVL 8-mode steady-state simulation of the U.S. EPA heavy-duty transient test procedure. The experimental fuels included diesel fuels obtained from different sources with various natural cetane ratings as well as a number of fuels blended by adding two cetane improvers into three base fuels. The two cetane improvers we used were a nitrate-type additive and a peroxide-type additive. Increasing the cetane number resulted in a general decrease in NOx emissions. Similar reductions in NOx emissions were observed with increasing cetane number for all the base fuels irrespective of the cetane improver used in the fuel.

The demand for light weight vehicles continues to stimulate extensive research into the development of light weight casting alloys and optimization of their manufacturing processes. Of primary relevance are Aluminum (Al) and Magnesium (Mg) based alloys, which have successfully replaced selected iron based castings in automobiles. However, optimization of as-cast microstructure, processing and performance remains a challenge for some Al-based alloys. In this context, placement of chills in castings has been frequently used to locally manipulate the solidification conditions and microstructure of a casting. In this work, the effect of using an active copper chill on the residual strain profile of a sand-cast B319 aluminum alloy was investigated. Wedge-shaped castings were produced with three different cooling conditions: copper plate chill, copper pipe with cooling water and no chill (baseline).

A widely held belief in the combustion community is that the chemical and hydrodynamic structure of a stretched laminar premixed flame can be preserved in a turbulent flow field over a range of conditions collectively known as the flamelet regime, and the homogeneous charge spark-ignition engine combustion falls within the domain of this regime. The major assumption in the laminar flamelet concept as applied to the turbulent premixed flames is that the flame front behaves as a constant-property passive scalar surface, and an increase in the wrinkled flame surface area with increasing turbulence intensity is the dominant mechanism for the observed flame velocity enhancement. The two approaches that have been recently used for estimating a measure of the wrinkled flame surface area in spark-ignition engines and other premixed flames are the flame surface density concept and fractal geometry.