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A 2003 heavy-duty diesel engine (2002 emissions level) was used to test a representative biodiesel fuel as well as the methyl esters of several different fatty acids. The fuel variables included degree of saturation, the oxygen content, and carbon chain length. In addition, two pure normal paraffins with the corresponding chain lengths of two of the methyl esters were also tested to determine the impact of chain length. The dependent variables were the NOx and the particulate emissions (PM). The results indicated that the primary fuel variable affecting the emissions is the oxygen content. The emissions results showed that the highest oxygen content test fuel had the lowest emissions of both NOx and PM. As compared to the baseline diesel fuel the NOx emissions were reduced by 5 percent and the PM emissions were reduced by 83 percent.

A low pressure fuel distillation system is proposed for extracting a high-volatility fraction of gasoline, and to improve start-up and warm-up behavior of SI engines. More complicated methods for generating high-volatility start-up fuels have demonstrated improved cold start driveability and reduced HC emissions, but so far they have not been put into mass production. In this project, a ‘bench-top’ apparatus was used to investigate the feasibility of using sub-atmospheric pressures to extract a lighter and more volatile fraction from the parent gasoline. A series of experiments was conducted to evaluate the characteristics of the extracted fuel vapor as a function of temperature and pressure. The sensitivity to different brands and grades of gasoline was also explored. The results show that the extracted fuel consists mostly of C5 and C6 compounds, and that its Molecular Weight and Stoichiometric A/F ratio show little sensitivity to the pressure level used for the extraction.

Southwest Research Institute (SwRI) is exploring the feasibility of extending the performance and fuel efficiency of the spark ignition (SI) engine to match that of the emission constrained compression (CI) engine, whilst retaining the cost effective 3-way stoichiometric aftertreatment systems associated with traditional SI light duty engines. The engine concept, which has a relatively high compression ratio and uses heavy EGR, is called “HEDGE”, i.e. High Efficiency Durable Gasoline Engine. Whereas previous SwRI papers have been medium and heavy duty development focused, this paper uses results from simulations, with some test bed correlations, to predict multicylinder torque curves, brake thermal efficiency and NOx emissions as well as knock limit for light and medium duty applications.

SwRI has developed a new technology concept involving the use of high EGR rates coupled with a high-energy ignition system in a gasoline engine to improve fuel economy and emissions. Based on a single-cylinder study [1], this study extends the concept of a high compression ratio gasoline engine with EGR rates > 30% and a high-energy ignition system to a multi-cylinder engine. A 2000 MY Isuzu Duramax 6.6 L 8-cylinder engine was converted to run on gasoline with a diesel pilot ignition system. The engine was run at two compression ratios, 17.5:1 and 12.5:1 and with two different EGR systems - a low-pressure loop and a high pressure loop. A high cetane number (CN) diesel fuel (CN=76) was used as the ignition source and two different octane number (ON) gasolines were investigated - a pump grade 91 ON ((R+M)/2) and a 103 ON ((R+M)/2) racing fuel.

Homogeneous Charge Compression Ignition (HCCI) experiments were performed in a variable compression ratio single cylinder engine. This is the fourth paper resulting from work performed at Southwest Research Institute in this HCCI engine. The experimental variables, in addition to speed and load, included compression ratio, EGR level, intake manifold pressure and temperature, fuel introduction location, and fuel composition. Mixture preparation and start of reaction control were identified as fundamental problems that required non-traditional mixture preparation and control strategies. The effects of the independent variable on the start of reaction have been documented. For fuels that display significant pre-flame reactions, the start of the pre-flame reactions is controlled primarily by the selection of the fuel and the temperature history of the fuel air mixture.

A technology path has been identified for development of a high efficiency, durable, gasoline engine, targeted at achieving performance and emissions levels necessary to meet heavy-duty, on-road standards of the foreseeable future. Initial experimental and numerical results for the proposed technology concept are presented. This work summarizes internal research efforts conducted at Southwest Research Institute. An alternative combustion system has been numerically and experimentally examined. The engine utilizes gasoline as the fuel, with a combination of enabling technologies to provide high efficiency operation at ultra-low emissions levels. The concept is based upon very highly-dilute combustion of gasoline at high compression ratio and boost levels. Results from the experimental program have demonstrated engine-out NOx emissions of 0.06 g/hp/hr, at single-cylinder brake thermal efficiencies (BTE) above thirty-four percent.

The engine-out emissions and fuel consumption rates for a modern, heavy-duty diesel engine were compared when fueling with a conventional diesel fuel and three water-blend-fuel emulsions. Four different fuels were studied: (1) a conventional diesel fuel, (2) PuriNOx,™ a water-fuel emulsion using the same conventional diesel fuel, but having 20% water by mass, and (3,4) two other formulations of the PuriNOx™ fuel that contained proprietary chemical additives intended to improve combustion efficiency and emissions characteristics. The emissions data were acquired with three different injection-timing strategies using the AVL 8-Mode steady-state test method in a Caterpillar 3176 engine, which had a calibration that met the 1998 nitrogen oxides (NOX) emissions standard.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

The impingement of liquid fuel onto the surfaces of the combustion chamber (wall-wetting) has been shown to be an important source of HC emissions from direct-injected SI engines, and can even result in pool fires and diffusion flames. Some degree of wall wetting, particularly on the piston top, is believed to occur in every current DIG engine design, but the behavior of the wall-bound fuel throughout the engine cycle is poorly understood. The goal of this study was to gain a better understanding of the fundamental interaction between liquid fuel droplets and the piston under engine-like conditions, by observing the vaporization of individual fuel drops as the surface temperature and ambient pressures were varied in a controlled environment. The vaporization of several single-component fuels, binary mixtures, and multi-component fuels was examined in the range of surface temperatures between 50 and 300 °C and ambient pressures between 50 and 1270 kPa (abs).

An experimental investigation of the effects of partial premixed charge compression ignition (PCCI) combustion and EGR temperature was conducted on a Caterpillar C-12 heavy-duty diesel engine (HDDE). The addition of EGR and PCCI combustion resulted in significant NOx reductions over the AVL 8-mode test. The lowest weighted BSNOx achieved was 2.55 g/kW-hr (1.90 g/hp-hr) using cooled EGR and 20% port fuel injection (PFI). This represents a 54% reduction compared to the stock engine. BSHC and BSCO emissions increased by a factor of 8 and 10, respectively, compared to the stock engine. BSFC also increased by 7.7%. In general, BSHC, BSCO, BSPM, and BSFC increased linearly with the amount of port-injected fuel.

A new combustion concept has been developed and tested for improving the low to moderate load efficiency and NOx emissions of natural gas engines. This concept involves operation of a dual-fuel natural gas engine on Homogeneous Charge Compression Ignition (HCCI) in the load regime of idle up to 35 % of the peak torque. A dual-fuel approach is used to control the combustion phasing of the engine during HCCI operation, and conventional spark-ignited natural gas combustion is used for the high-load regime. This concept has resulted in an engine with power output and high-load fuel efficiency that are unchanged from the base engine, but with a 10 - 15 % improvement to the low to moderate load fuel efficiency. In addition, the engine-out NOx emissions during HCCI operation are over 90% lower than on spark-ignited natural gas operation over the equivalent load range.

The U.S. Environmental Protection Agency (EPA) formed a Heavy-Duty Engine Working Group (HDEWG) in the Mobile Sources Technical Advisory Subcommittee in 1995. The goal of the HDEWG was to help define the role of the fuel in meeting the future emissions standards in advanced technology engines (beyond 2004 regulated emissions levels). A three-phase program was developed. This paper presents the results of the statistical analysis of the data collected in the Phase II program. Included is a description of the design of the fuel test matrix, and a listing of the regression equations developed to predict emissions as a function of fuel density, cetane number, monoaromatics, and polyaromatics. Also included is a description of selected analyses of the emissions from a smaller set of fuel data that allowed direct comparison of the effects of natural and boosted cetane number.

In 1995, US Environmental Protection Agency (EPA) formed the Heavy-Duty Engine Working Group (HDEWG). The objective of the group was to assess the role diesel fuel could play in meeting exhaust emission standards proposed for model year 2004+ heavy-duty diesel engines. The group developed a three-phase program to achieve this objective. This paper describes the development of test fuels used in Phase 2 of the EPA HDEWG Program to investigate the effect of fuel properties on heavy-duty diesel engine emissions. It discusses the design of the fuel matrix, reviews the process of test fuel preparation and presents the results of a multi-laboratory fuel analysis program. Fuel properties selected for investigation included density, cetane number, mono- and polyaromatic hydrocarbon content.

In 1997 the US EPA formed a Heavy-Duty Engine Working Group (HDEWG) in the Mobile Sources Technical Advisory Subcommittee to address the questions related to fuel property effects on heavy-duty diesel engine emissions. The Working Group consisted of members from EPA and the oil refining and engine manufacturing industries. The goal of the Working Group was to help define the role of the fuel in meeting the future emissions standards in advanced technology engines (beyond 2004 regulated emissions levels). To meet this objective a three-phase program was developed. Phase I was designed to demonstrate that a prototype engine, located at Southwest Research Institute, represented similar emissions characteristics to that of certain manufacturers prototype engines. Phase II was designed to document the effects of selected fuel properties using a statistically designed fuel matrix in which cetane number, density, and aromatic content and type were the independent variables.

Recent advances in Variable Valve Actuation (VVA) methods have led to development of optimized valve timing strategies for a broad range of engine operating conditions. This study focuses on the cold-start period, which begins at engine cranking and lasts for approximately 1 minute thereafter. Cold-start is characterized by poor mixture preparation due to low component temperatures, aggravated by fixed valve timing which has historically been compromised to give optimal warm engine operation. In this study, intake cam phasing was varied to explore the potential benefit in hydrocarbon emissions and driveability obtainable for cold-start. A simple experimental approach was used to investigate the potential emissions benefits realizable through intake cam phasing. High speed cylinder pressure and Fast Flame Ionization Detector (FFID) engine-out hydrocarbon (HC) measurements were made to characterize instantaneous cold-start emissions and driveability.

The specific goal of this project was to determine if there is a difference in the lube oil degradation rates in a heavy-duty diesel engine equipped with an EGR system, as compared to the same configuration of the engine, but minus the EGR system. A secondary goal was to develop FTIR analysis of used lube oil as a sensitive technique for rapid evaluation of the degradation properties of lubricants. The test engine selected for this work was a Caterpillar 3176 engine. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to meet the 2004 emissions standards. The most significant changes in the lubricant occurred during the first 50-100 hours of operation. The results clearly demonstrated that the use of EGR has a significant impact on the degradation of the engine lubricant.

Large reductions in low-load NOx emissions can be obtained by replacing conventional Diesel or spark ignited combustion by HCCI combustion in reciprocating engines. Currently, HCCI combustion is limited to operating conditions with lean air/fuel ratios or large amounts of EGR. However, a numerical model shows that, even if high equivalence ratio HCCI operation were satisfactorily attained, the NOx reduction potential vs. DI-Diesel combustion would be much smaller. Thus, high-load HCCI operation may best be obtained through highly boosted fuel-lean operation. Alternatively, HCCI combustion may be suited well for “dual mode” engine applications, in which spark ignition or conventional Diesel combustion is used to obtain full load. Avoiding wall impingement with heavy fuels is critical for achieving good emissions and fuel consumption, and it appears that a large degree of mixture inhomogeneity can be tolerated from a NOx benefit standpoint.

The effect of combustion chamber wall-wetting on the emissions of unburned and partially-burned hydrocarbons (HCs) from gasoline-fueled SI engines was investigated experimentally. A spark-plug mounted directional injection probe was developed to study the fate of liquid fuel which impinges on different surfaces of the combustion chamber, and to quantify its contribution to the HC emissions from direct-injected (DI) and port-fuel injected (PFI) engines. With this probe, a controlled amount of liquid fuel was deposited on a given location within the combustion chamber at a desired crank angle while the engine was operated on pre-mixed LPG. Thus, with this technique, the HC emissions due to in-cylinder wall wetting were studied independently of all other HC sources. Results from these tests show that the location where liquid fuel impinges on the combustion chamber has a very important effect on the resulting HC emissions.

The engine selected for this work was a Caterpillar 3176 engine. Engine exhaust emissions, performance, and heat release rates were measured as functions of engine configuration, engine speed and load. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to achieve a NOx emissions level of 2.5 gm/hp-hr. Measurements were performed at 7 different steady-state, speed-load conditions on thirteen different test fuels. The fuel matrix was statistically designed to independently examine the effects of the targeted fuel properties. Cetane number was varied from 40 to 55, using both natural cetane number and cetane percent improver additives. Aromatic content ranged from 10 to 30 percent in two different forms, one in which the aromatics were predominantly mono-aromatic species and the other, where a significant fraction of the aromatics were either di- or tri-aromatics.

A liquid-phase port injection system for liquefied petroleum gas (LPG) generally consists of a fuel storage tank with extended capability of operating up to 600 psi, a fuel pump, and suitable fuel lines to and from the LPG fuel injectors mounted in the fuel rail manifold. Port injection of LPG in the liquid phase is attractive due to engine emissions and performance benefits. However, maintaining the LPG in the liquid phase at under-hood conditions and re-starting after hot soak can be difficult. Multiphase behavior within a liquid-phase LPG injection system was investigated computationally and experimentally. A commercial chemical equilibrium code (ASPEN PLUS™) was used to model various LPG compositions under operating conditions.